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An Overlooked Pathway in 1,3‐Dipolar Cycloadditions of Diazoalkanes with Enamines

Methyl diazoacetate reacts with 1‐(N‐pyrrolidino)cycloalkenes to give products of 1,3‐dipolar cycloadditions and azo couplings. The kinetics and mechanisms of these reactions were investigated by NMR spectroscopy and DFT calculations. Orthogonal π‐systems in the 1,3‐dipoles of the propargyl‐allenyl...

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Detalles Bibliográficos
Autores principales:	Li, Le, Mayer, Peter, Stephenson, David S., Ofial, Armin R., Mayer, Robert J., Mayr, Herbert
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9306659/ https://www.ncbi.nlm.nih.gov/pubmed/35023245 http://dx.doi.org/10.1002/anie.202117047

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