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Factors Governing the Catalytic Insertion of CO(2) into Arenes – A DFT Case Study for Pd and Pt Phosphane Sulfonamido Complexes
The potential of Pd/Pt complexes for catalytic carboxylation of arenes with CO(2) is investigated by means of computational chemistry. Recently we reported that the bis[(2‐methoxyphenyl)phosphino]‐benzenesulfonamido palladium complex 1 inserts CO(2) reversibly in its Pd−C(aryl) bond generating carbo...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9310616/ https://www.ncbi.nlm.nih.gov/pubmed/35188311 http://dx.doi.org/10.1002/chem.202104375 |