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Can Water Act as a Nucleophile in CO Oxidation Catalysed by Mo/Cu CO‐Dehydrogenase? Answers from Theory

The aerobic CO dehydrogenase from Oligotropha carboxidovorans is an environmentally crucial bacterial enzyme for maintenance of subtoxic concentration of CO in the lower atmosphere, as it allows for the oxidation of CO to CO(2) which takes place at its Mo−Cu heterobimetallic active site. Despite ext...

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Detalles Bibliográficos
Autores principales:	Rovaletti, Anna, Moro, Giorgio, Cosentino, Ugo, Ryde, Ulf, Greco, Claudio
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9310835/ https://www.ncbi.nlm.nih.gov/pubmed/35170169 http://dx.doi.org/10.1002/cphc.202200053

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