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Zinc‐Promoted ZnMe/ZnPh Exchange in Eight‐Coordinate [Ru(PPh(3))(2)(ZnMe)(4)H(2)]

The syntheses, reactivity and electronic structure analyses of [Ru(PPh(3))(2)(ZnMe)(4)H(2)], 1 a, and [Ru(PPh(3))(2)(ZnPh)(4)H(2)], 2 b, are reported. 1 a exhibits an 8‐coordinate Ru centre with axial phosphines and a symmetrical (2 : 2) arrangement of ZnMe ligands in the equatorial plane. The ZnMe...

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Detalles Bibliográficos
Autores principales:	Sotorrios, Lia, Miloserdov, Fedor M., Pécharman, Anne‐Frédérique, Lowe, John P., Macgregor, Stuart A., Mahon, Mary F., Whittlesey, Michael K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9311408/ https://www.ncbi.nlm.nih.gov/pubmed/35213937 http://dx.doi.org/10.1002/anie.202117495

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