Synthesis of Fe(III) and Fe(IV) Cyanide Complexes Using Hypervalent Iodine Reagents as Cyano‐Transfer One‐Electron Oxidants

We disclose a new reactivity mode for electrophilic cyano λ(3)‐iodanes as group transfer one‐electron oxidants to synthesize Fe(III) and Fe(IV) cyanide complexes. The inherent thermal instability of high‐valent Fe(IV) compounds without π‐donor ligands (such as oxido (O(2−)), imido (RN(2−)) or nitrid...

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Detalles Bibliográficos
Autores principales: Souilah, Charafa, Jannuzzi, Sergio A. V., Demirbas, Derya, Ivlev, Sergei, Swart, Marcel, DeBeer, Serena, Casitas, Alicia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9313551/
https://www.ncbi.nlm.nih.gov/pubmed/35285116
http://dx.doi.org/10.1002/anie.202201699

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