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Calix[4]pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers

High molar weight polyphosphinoboranes represent materials with auspicious properties, but their preparation requires transition metal‐based catalysts. Here, calix[4]pyrrolato aluminate is shown to induce the dehydropolymerization of phosphine boranes to high molar mass polyphosphinoboranes (up to M...

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Detalles Bibliográficos
Autores principales: Schön, Florian, Sigmund, Lukas M., Schneider, Friederike, Hartmann, Deborah, Wiebe, Matthew A., Manners, Ian, Greb, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9313825/
https://www.ncbi.nlm.nih.gov/pubmed/35235698
http://dx.doi.org/10.1002/anie.202202176