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In Vitro Biosynthesis of the [Fe]‐Hydrogenase Cofactor Verifies the Proposed Biosynthetic Precursors

In the FeGP cofactor of [Fe]‐hydrogenase, low‐spin Fe(II) is in complex with two CO ligands and a pyridinol derivative; the latter ligates the iron with a 6‐acylmethyl substituent and the pyridinol nitrogen. A guanylylpyridinol derivative, 6‐carboxymethyl‐3,5‐dimethyl‐4‐guanylyl‐2‐pyridinol (3), is...

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Detalles Bibliográficos
Autores principales:	Schaupp, Sebastian, Arriaza‐Gallardo, Francisco J., Pan, Hui‐jie, Kahnt, Jörg, Angelidou, Georgia, Paczia, Nicole, Costa, Kyle, Hu, Xile, Shima, Seigo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314073/ https://www.ncbi.nlm.nih.gov/pubmed/35286742 http://dx.doi.org/10.1002/anie.202200994

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