Cargando…

Asymmetric Synthesis of Axially Chiral C−N Atropisomers

Molecules with restricted rotation around a single bond or atropisomers are found in a wide number of natural products and bioactive molecules as well as in chiral ligands for asymmetric catalysis and smart materials. Although most of these compounds are biaryls and heterobiaryls displaying a C−C st...

Descripción completa

Detalles Bibliográficos
Autores principales:	Rodríguez‐Salamanca, Patricia, Fernández, Rosario, Hornillos, Valentín, Lassaletta, José M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Reviews
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314733/ https://www.ncbi.nlm.nih.gov/pubmed/35191558 http://dx.doi.org/10.1002/chem.202104442

Ejemplares similares

Enantioselective Synthesis of Atropisomers by Oxidative Aromatization with Central-to-Axial Conversion of Chirality
por: Lemaitre, Clément, et al.
Publicado: (2023)

Asymmetric synthesis of dibenzo[b,d]azepines by Cu-catalyzed reductive or borylative cyclization
por: Rodríguez-Salamanca, Patricia, et al.
Publicado: (2021)

Conformational enantiodiscrimination for asymmetric construction of atropisomers
por: Cen, Shouyi, et al.
Publicado: (2022)

Enzymatic Desymmetrising Redox Reactions for the Asymmetric Synthesis of Biaryl Atropisomers
por: Staniland, Samantha, et al.
Publicado: (2014)

Pd-Catalyzed Dynamic Kinetic Asymmetric Cross-Coupling of Heterobiaryl Bromides with N-Tosylhydrazones
por: Kattela, Shivashankar, et al.
Publicado: (2022)

Biocatalytic Enantioselective Synthesis of Atropisomers
por: Watts, Olivia F. B., et al.
Publicado: (2022)

Enantioselective Synthesis of Five-Membered-Ring Atropisomers with a Chiral Rh(III) Complex
por: Shaaban, Saad, et al.
Publicado: (2020)

Atroposelective synthesis of N-aryl peptoid atropisomers via a palladium(ii)-catalyzed asymmetric C–H alkynylation strategy
por: Wu, Yong-Jie, et al.
Publicado: (2021)

Bifunctional organocatalysts for the asymmetric synthesis of axially chiral benzamides
por: Miyaji, Ryota, et al.
Publicado: (2017)

Enantiospecific Syntheses of Congested Atropisomers through Chiral Bis(aryne) Synthetic Equivalents
por: Dauvergne, Guillaume, et al.
Publicado: (2022)

Asymmetric synthesis of N–N axially chiral compounds via organocatalytic atroposelective N-acylation
por: Lin, Wei, et al.
Publicado: (2021)

Separation of atropisomers by chiral liquid chromatography and thermodynamic analysis of separation mechanism()
por: Zhang, Ling, et al.
Publicado: (2017)

Recent advances in the asymmetric phosphoric acid-catalyzed synthesis of axially chiral compounds
por: Woldegiorgis, Alemayehu Gashaw, et al.
Publicado: (2021)

Asymmetric Synthesis of Axially Chiral Molecules via Organocatalytic Cycloaddition and Cyclization Reactions
por: Cai, Wei-Yun, et al.
Publicado: (2023)

Dirhodium(II)/Phosphine Catalyst with Chiral Environment at Bridging Site and Its Application in Enantioselective Atropisomer Synthesis
por: Shi, Lei, et al.
Publicado: (2023)

Synthesis of axially chiral gold complexes and their applications in asymmetric catalyses
por: Sun, Yin-wei, et al.
Publicado: (2013)

o‐Quinodimethane Atropisomers: Enantioselective Synthesis and Stereospecific Transformation
por: Dong, Jianyang, et al.
Publicado: (2022)

Transient-axial-chirality controlled asymmetric rhodium-carbene C(sp(2))-H functionalization for the synthesis of chiral fluorenes
por: Dong, Kuiyong, et al.
Publicado: (2020)

Asymmetric synthesis of biaryl atropisomers by dynamic resolution on condensation of biaryl aldehydes with (−)-ephedrine or a proline-derived diamine
por: Bracegirdle, Ann, et al.
Publicado: (2008)

Asymmetric rhodium-catalyzed click cycloaddition to access C–N axially chiral N-triazolyl indoles
por: Zhou, Li, et al.
Publicado: (2023)

Solid Phase Deracemization of an Atropisomer
por: Engwerda, Anthonius H. J., et al.
Publicado: (2017)

Atroposelective Synthesis of Axially Chiral N‐Arylpyrroles by Chiral‐at‐Rhodium Catalysis
por: Ye, Chen‐Xi, et al.
Publicado: (2020)

Organocatalytic asymmetric N-sulfonyl amide C-N bond activation to access axially chiral biaryl amino acids
por: Wang, Guanjie, et al.
Publicado: (2020)

Copper-catalyzed asymmetric C(sp(2))–H arylation for the synthesis of P- and axially chiral phosphorus compounds
por: Yan, Shao-Bai, et al.
Publicado: (2023)

Dynamic Kinetic Resolution of Indole-Based Sulfenylated Heterobiaryls by Rhodium-Catalyzed Atroposelective Reductive Aldol Reaction
por: Rodríguez-Franco, Carlos, et al.
Publicado: (2023)

Asymmetric allylic substitution–isomerization to axially chiral enamides via hydrogen-bonding assisted central-to-axial chirality transfer
por: Sun, Chao, et al.
Publicado: (2020)

Highly atroposelective synthesis of nonbiaryl naphthalene-1,2-diamine N-C atropisomers through direct enantioselective C-H amination
por: Bai, He-Yuan, et al.
Publicado: (2019)

Facile synthesis of axially chiral styrene-type carboxylic acids via palladium-catalyzed asymmetric C–H activation
por: Yang, Chi, et al.
Publicado: (2021)

DNA as a Chiral Scaffold for Asymmetric Synthesi
por: Park, Soyoung, et al.
Publicado: (2012)

Carbamate-directed benzylic lithiation for the diastereo- and enantioselective synthesis of diaryl ether atropisomers
por: Page, Abigail, et al.
Publicado: (2011)

Inherently Chiral Calixarenes: Synthesis, Optical Resolution, Chiral Recognition and Asymmetric Catalysis
por: Li, Shao-Yong, et al.
Publicado: (2011)

Enantioselective construction of ortho-sulfur- or nitrogen-substituted axially chiral biaryls and asymmetric synthesis of isoplagiochin D
por: Yang, He, et al.
Publicado: (2022)

Catalytic Enantioselective Synthesis of N-C Axially Chiral N-(2,6-Disubstituted-phenyl)sulfonamides through Chiral Pd-Catalyzed N-Allylation
por: Fukasawa, Sota, et al.
Publicado: (2022)

Diaryl-Pyrano-Chromenes Atropisomers: Stereodynamics and Conformational Studies
por: Ciogli, Alessia, et al.
Publicado: (2023)

Atropisomers of meso Tetra(N‐Mesyl Pyrrol‐2‐yl) Porphyrins: Synthesis, Isolation and Characterization of All‐Pyrrolic Porphyrins
por: Zhu, Leiming, et al.
Publicado: (2020)

Organocatalytic atroposelective synthesis of axially chiral styrenes
por: Zheng, Sheng-Cai, et al.
Publicado: (2017)

Phosphite mediated asymmetric N to C migration for the synthesis of chiral heterocycles from primary amines
por: Rani, Soniya, et al.
Publicado: (2021)

Advances in Atroposelectively De Novo Synthesis of Axially Chiral Heterobiaryl Scaffolds
por: Zhang, Xiaoke, et al.
Publicado: (2022)

A survey of chiral hypervalent iodine reagents in asymmetric synthesis
por: Ghosh, Soumen, et al.
Publicado: (2018)

Chiral Thioureas—Preparation and Significance in Asymmetric Synthesis and Medicinal Chemistry
por: Steppeler, Franz, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_loc765q0lapvp5ehbmhiv92id7