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Catalytic Asymmetric β‐Oxygen Elimination
A catalytic enantioselective β‐O‐elimination reaction is reported in the form of a zirconium‐catalyzed asymmetric opening of meso‐ketene acetals. Furthermore, a regiodivergent β‐O‐elimination is demonstrated. The reaction proceeds under mild conditions, at low catalyst loadings, and produces chiral...
Autores principales: | Matt, Christof, Orthaber, Andreas, Streuff, Jan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314826/ https://www.ncbi.nlm.nih.gov/pubmed/35263503 http://dx.doi.org/10.1002/anie.202114044 |
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