Cargando…

Catalytic Asymmetric β‐Oxygen Elimination

A catalytic enantioselective β‐O‐elimination reaction is reported in the form of a zirconium‐catalyzed asymmetric opening of meso‐ketene acetals. Furthermore, a regiodivergent β‐O‐elimination is demonstrated. The reaction proceeds under mild conditions, at low catalyst loadings, and produces chiral...

Descripción completa

Detalles Bibliográficos
Autores principales: Matt, Christof, Orthaber, Andreas, Streuff, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314826/
https://www.ncbi.nlm.nih.gov/pubmed/35263503
http://dx.doi.org/10.1002/anie.202114044

Ejemplares similares