Polycations Stabilised by Borosulfates: [Au(3)Cl(4)][B(S(2)O(7))(2)] and the One‐Dimensional Metal [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3))

(SO(4))‐rich silicate analogue borosulfates are able to stabilise cationic cluster‐like and chain‐like aggregates. Single crystals of [Au(3)Cl(4)][B(S(2)O(7))(2)] and [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3)) were obtained by solvothermal reaction with SO(3), and the electronic properties were investigate...

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Autores principales: Sutorius, Stefan, van Gerven, David, Olthof, Selina, Rasche, Bertold, Bruns, Jörn
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314955/
https://www.ncbi.nlm.nih.gov/pubmed/35262987
http://dx.doi.org/10.1002/chem.202200004
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author Sutorius, Stefan
van Gerven, David
Olthof, Selina
Rasche, Bertold
Bruns, Jörn
author_facet Sutorius, Stefan
van Gerven, David
Olthof, Selina
Rasche, Bertold
Bruns, Jörn
author_sort Sutorius, Stefan
collection PubMed
description (SO(4))‐rich silicate analogue borosulfates are able to stabilise cationic cluster‐like and chain‐like aggregates. Single crystals of [Au(3)Cl(4)][B(S(2)O(7))(2)] and [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3)) were obtained by solvothermal reaction with SO(3), and the electronic properties were investigated by means of density functional theory–based calculations. [Au(3)Cl(4)][B(S(2)O(7))(2)] exhibits a cluster‐like cation, and the cationic gold‐chloride strands in [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3)) are found to resemble one‐dimensional metallic wires. This is confirmed by polarisation microscopy.
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spelling pubmed-93149552022-07-30 Polycations Stabilised by Borosulfates: [Au(3)Cl(4)][B(S(2)O(7))(2)] and the One‐Dimensional Metal [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3)) Sutorius, Stefan van Gerven, David Olthof, Selina Rasche, Bertold Bruns, Jörn Chemistry Research Articles (SO(4))‐rich silicate analogue borosulfates are able to stabilise cationic cluster‐like and chain‐like aggregates. Single crystals of [Au(3)Cl(4)][B(S(2)O(7))(2)] and [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3)) were obtained by solvothermal reaction with SO(3), and the electronic properties were investigated by means of density functional theory–based calculations. [Au(3)Cl(4)][B(S(2)O(7))(2)] exhibits a cluster‐like cation, and the cationic gold‐chloride strands in [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3)) are found to resemble one‐dimensional metallic wires. This is confirmed by polarisation microscopy. John Wiley and Sons Inc. 2022-03-23 2022-04-19 /pmc/articles/PMC9314955/ /pubmed/35262987 http://dx.doi.org/10.1002/chem.202200004 Text en © 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Research Articles
Sutorius, Stefan
van Gerven, David
Olthof, Selina
Rasche, Bertold
Bruns, Jörn
Polycations Stabilised by Borosulfates: [Au(3)Cl(4)][B(S(2)O(7))(2)] and the One‐Dimensional Metal [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3))
title Polycations Stabilised by Borosulfates: [Au(3)Cl(4)][B(S(2)O(7))(2)] and the One‐Dimensional Metal [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3))
title_full Polycations Stabilised by Borosulfates: [Au(3)Cl(4)][B(S(2)O(7))(2)] and the One‐Dimensional Metal [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3))
title_fullStr Polycations Stabilised by Borosulfates: [Au(3)Cl(4)][B(S(2)O(7))(2)] and the One‐Dimensional Metal [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3))
title_full_unstemmed Polycations Stabilised by Borosulfates: [Au(3)Cl(4)][B(S(2)O(7))(2)] and the One‐Dimensional Metal [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3))
title_short Polycations Stabilised by Borosulfates: [Au(3)Cl(4)][B(S(2)O(7))(2)] and the One‐Dimensional Metal [Au(2)Cl(4)][B(S(2)O(7))(2)](SO(3))
title_sort polycations stabilised by borosulfates: [au(3)cl(4)][b(s(2)o(7))(2)] and the one‐dimensional metal [au(2)cl(4)][b(s(2)o(7))(2)](so(3))
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9314955/
https://www.ncbi.nlm.nih.gov/pubmed/35262987
http://dx.doi.org/10.1002/chem.202200004
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