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Trapping X‐ray Radiation Damage from Homolytic Se−C Bond Cleavage in BnSeSeBn Crystals (Bn=benzyl, CH(2)C(6)H(5))

Irradiation of dibenzyl diselenide BnSeSeBn with X‐ray or UV‐light cleaves the Se−C and the Se−Se bonds, inducing stable and metastable radical states. They are inevitably important to all natural and life sciences. Structural changes due to X‐ray‐induced Se−C bond‐cleavage could be pin‐pointed in v...

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Detalles Bibliográficos
Autores principales: Schürmann, Christian J., Teuteberg, Thorsten L., Stückl, A. Claudia, Ruth, Paul Niklas, Hecker, Fabian, Herbst‐Irmer, Regine, Mata, Ricardo A., Stalke, Dietmar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9320817/
https://www.ncbi.nlm.nih.gov/pubmed/35417063
http://dx.doi.org/10.1002/anie.202203665