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Metal‐Free Photochemical Olefin Isomerization of Unsaturated Ketones via 1,5‐Hydrogen Atom Transfer

The photochemical isomerization of α,β‐ to β,γ‐unsaturated ketones through a 1,5‐hydrogen atom transfer mechanism under mild conditions with high efficiency and selectivity is reported. The reaction is carried out in the absence of metal catalysts or other additives, and its stereoselectivity can be...

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Detalles Bibliográficos
Autores principales: Manikandan, Rajendran, Phatake, Ravindra S., Lemcoff, N. Gabriel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321148/
https://www.ncbi.nlm.nih.gov/pubmed/35325491
http://dx.doi.org/10.1002/chem.202200634

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