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Evolution of the Dearomative Functionalization of Activated Quinolines and Isoquinolines: Expansion of the Electrophile Scope

Herein we disclose a mild protocol for the reductive functionalisation of quinolinium and isoquinolinium salts. The reaction proceeds under transition‐metal‐free conditions as well as under rhodium catalysis with very low catalyst loadings (0.01 mol %) and uses inexpensive formic acid as the termina...

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Detalles Bibliográficos
Autores principales: Kischkewitz, Marvin, Marinic, Bruno, Kratena, Nicolas, Lai, Yonglin, Hepburn, Hamish B., Dow, Mark, Christensen, Kirsten E., Donohoe, Timothy J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321684/
https://www.ncbi.nlm.nih.gov/pubmed/35560761
http://dx.doi.org/10.1002/anie.202204682

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