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Disclosing Cyclic(Alkyl)(Amino)Carbenes as One‐Electron Reductants: Synthesis of Acyclic(Amino)(Aryl)Carbene‐Based Kekulé Diradicaloids

Herein, we disclose cyclic(alkyl)(amino)carbenes (CAACs) to be one‐electron reductants under the formation of a transient radical cation as indicated by EPR spectroscopy. The disclosed CAAC reducing reactivity was used to synthesize acyclic(amino)(aryl)carbene‐based Thiele and Chichibabin hydrocarbo...

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Detalles Bibliográficos
Autores principales:	Maiti, Avijit, Elvers, Benedict J., Bera, Sachinath, Lindl, Felix, Krummenacher, Ivo, Ghosh, Prasanta, Braunschweig, Holger, Yildiz, Cem B., Schulzke, Carola, Jana, Anukul
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321839/ https://www.ncbi.nlm.nih.gov/pubmed/35262232 http://dx.doi.org/10.1002/chem.202104567

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