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Pd‐Catalyzed Difluoromethylations of Aryl Boronic Acids, Halides, and Pseudohalides with ICF(2)H Generated ex Situ

An expedient ex‐situ generation of difluoroiodomethane (DFIM) and its immediate use in a Pd‐catalyzed difluoromethylation of aryl boronic acids and ester derivatives in a two‐chamber reactor is reported. Heating a solution of bromodifluoroacetic acid with sodium iodide in sulfolane proved to be effe...

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Detalles Bibliográficos
Autores principales:	Gedde, Oliver R., Bonde, Andreas, Golbækdal, Peter I., Skrydstrup, Troels
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321866/ https://www.ncbi.nlm.nih.gov/pubmed/35388933 http://dx.doi.org/10.1002/chem.202200997

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