Cargando…

Halogenation of the Hexaphosphabenzene Complex [(Cp*Mo)(2)(μ,η(6):η(6)‐P(6))]: Snapshots on the Reaction Progress

The oxidation of [(Cp*Mo)(2)(μ,η(6):η(6)‐P(6))] (1) with halogens or halogen sources was investigated. The iodination afforded the ionic complexes [(Cp*Mo)(2)(μ,η(3):η(3)‐P(3))(μ,η(1):η(1):η(1):η(1)‐P(3)I(3))][X] (X=I(3) (−), I(−)) (2) and [(Cp*Mo)(2)(μ,η(4):η(4)‐P(4))(μ‐PI(2))][I(3)] (3), while the...

Descripción completa

Detalles Bibliográficos
Autores principales:	Garbagnati, Anna, Seidl, Michael, Balázs, Gábor, Scheer, Manfred
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9321898/ https://www.ncbi.nlm.nih.gov/pubmed/35348263 http://dx.doi.org/10.1002/chem.202200669

Ejemplares similares

Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)(2)(μ,η(6):η(6)-P(6))] Towards the “Naked” Cations Cu(+), Ag(+), and Tl(+)
por: Fleischmann, Martin, et al.
Publicado: (2015)

The Triple-Decker Complex [Cp*Fe(µ,η(5):η(5)-P(5))Mo(CO)(3)] as a Building Block in Coordination Chemistry
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2019)

Transformations of the cyclo-P(4) ligand in [Cp′′′Co(η(4)-P(4))]
por: Piesch, Martin, et al.
Publicado: (2020)

The Potential of the Diarsene Complex [(C(5)H(5))(2)Mo(2)(CO)(4)(μ,η(2)‐As(2))] as a Connector Between Silver Ions
por: Moussa, Mehdi Elsayed, et al.
Publicado: (2020)

Controlled introduction of functional groups at one P atom in [Cp*Fe(η(5)-P(5))] and release of functionalised phosphines
por: Reichl, Stephan, et al.
Publicado: (2023)

Mixed Organometallic–Organic Hybrid Assemblies Based on the Diarsene Complex [Cp(2)Mo(2)(CO)(4)(μ,η(2)‐As(2))], Ag(I) Salts and N‐Donor Organic Molecules
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2021)

Stabilization of Pentaphospholes as η(5)‐Coordinating Ligands
por: Riesinger, Christoph, et al.
Publicado: (2020)

The Butterfly Complex [{Cp*Cr(CO)(3)}(2)(μ,η(1:1)‐P(4))] as a Versatile Ligand and Its Unexpected P(1)/P(3) Fragmentation
por: Grünbauer, Rebecca, et al.
Publicado: (2020)

Bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo)
por: Moroz, Yurii S., et al.
Publicado: (2011)

Steric Switching From Photochemical to Thermal N(2) Splitting: A Computational Analysis of the Isomerization Reaction {(Cp(*))(Am)Mo}(2)(μ-η(1):η(1)-N(2)) → {(Cp(*))(Am)Mo}(2)(μ-N)(2)
por: Krewald, Vera
Publicado: (2019)

Crystal structure of the [(THF)Cs(μ-η(5):η(5)-Cp′)(3)Yb](n) oligomer
por: Huh, Daniel N., et al.
Publicado: (2020)

Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp(2)Mo(2)(CO)(4)(η(2)‐P(2))] Complex and Silver(I) Salts
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2017)

Halogenation and Nucleophilic Quenching: Two Routes to E−X Bond Formation in Cobalt Triple‐Decker Complexes (E=As, P; X=F, Cl, Br, I)
por: Garbagnati, Anna, et al.
Publicado: (2022)

Bis(η(6)-naphthalene)molybdenum(0)
por: Minyaev, Mikhail E., et al.
Publicado: (2012)

LHCb searches for the strong CP-violating decays η → ππ and η′ → ππ
por: Capriotti, L
Publicado: (2017)

Diantimony Complexes [Cp(R) (2)Mo(2)(CO)(4)(μ,η(2)‐Sb(2))] (Cp(R)=C(5)H(5), C(5)H(4) (t)Bu) as Unexpected Ligands Stabilizing Silver(I)( n ) (n=1–4) Monomers, Dimers and Chains
por: Shelyganov, Pavel A., et al.
Publicado: (2023)

The Potential of the Diphosphorus Complex [Cp(2)W(2)(CO)(4)(η(2)‐P(2))] as an Organometallic Connecter in Supramolecular Chemistry
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2019)

Tricarbonyl(η(6)-flavone)chromium(0)
por: van Tonder, Johannes H., et al.
Publicado: (2009)

(η(5)-Cyclopentadienyl)(η(6)-mesitylamine)ruthenium(II) hexafluoridophosphate
por: Becker, Eva, et al.
Publicado: (2009)

Di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(II)]
por: González-Torres, Yunuem, et al.
Publicado: (2009)

An Actinide Zintl Cluster: A Tris(triamidouranium)μ(3)-η(2):η(2):η(2)-Heptaphosphanortricyclane and Its Diverse Synthetic Utility**
por: Patel, Dipti, et al.
Publicado: (2013)

Taming a monomeric [Cu(η(6)-C(6)H(6))](+) complex with silylene
por: Parvin, Nasrina, et al.
Publicado: (2018)

The Diphosphorus Complex [Cp(2)Mo(2)(CO)(4)(η(2)‐P(2))] as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers
por: Moussa, Mehdi Elsayed, et al.
Publicado: (2016)

(η(5)-Pentamethylcyclopentadienyl)(η(6)-toluene)ruthenium(II) hexafluoridophosphate
por: O, Wylie W. N., et al.
Publicado: (2010)

(η(6)-Benzophenone)(η(5)-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate
por: Loughrey, Bradley T., et al.
Publicado: (2009)

A Cyclometalated NHC Iridium Complex Bearing a Cationic (η(5)‐Cyclopentadienyl)(η(6)‐phenyl)iron Backbone
por: Malchau, Christian, et al.
Publicado: (2021)

μ-η(2):η(2)-Peroxido-bis[nitratodioxidobis(pyrrolidin-2-one)uranium(VI)]
por: Takao, Koichiro, et al.
Publicado: (2010)

η(6)‐Metalated Aryl Iodides in Diels‐Alder Cycloaddition Reactions: Mode of Activation and Catalysis
por: Portela, Susana, et al.
Publicado: (2022)

Comparison of the catalytic activity for the Suzuki–Miyaura reaction of (η(5)-Cp)Pd(IPr)Cl with (η(3)-cinnamyl)Pd(IPr)(Cl) and (η(3)-1-t-Bu-indenyl)Pd(IPr)(Cl)
por: Melvin, Patrick R, et al.
Publicado: (2015)

(η(5)-Cyclopentadienyl)(η(6)-1,2-dipyrrolidin-1-ylbenzene)iron(II) hexafluoridophosphate
por: Jenkins, Hilary A., et al.
Publicado: (2009)

Synthesis and Analgesic Activity of η(6)-(Anisole)- Triscarbonyl-Chromium(0)
por: Andrade e Silva, Márcio Luís, et al.
Publicado: (1999)

Dichlorido(dimethyl sulfoxide-κS)(η(6)-mesitylene)ruthenium(II)
por: Oelkers, Benjamin, et al.
Publicado: (2011)

(η(6)-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II)
por: Muller, Alfred, et al.
Publicado: (2012)

Tri-μ-chlorido-bis[(η(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III)
por: Štěpnička, Petr, et al.
Publicado: (2011)

Acid/base triggered interconversion of μ-η(2):η(2)-peroxido and bis(μ-oxido) dicopper intermediates capped by proton-responsive ligands
por: Goswami, V. E., et al.
Publicado: (2017)

(η(5)-Pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(II) tetraphenylborate
por: Loughrey, Bradley T., et al.
Publicado: (2008)

Ruthenium(η(6),η(1)-arene-CH(2)-NHC) Catalysts for Direct Arylation of 2-Phenylpyridine with (Hetero)Aryl Chlorides in Water
por: Kaloğlu, Nazan, et al.
Publicado: (2018)

Naphthalene Exchange in [Re(η(6)‐napht)(2)](+) with Pharmaceuticals Leads to Highly Functionalized Sandwich Complexes [M(η(6)‐pharm)(2)](+) (M=Re/(99m)Tc)
por: Nadeem, Qaisar, et al.
Publicado: (2021)

Note on the γγ contribution to π0→e+e- and η→μ+μ-
por: Bergström, L, et al.
Publicado: (1984)

Tetraethylammonium trichlorido(η(6)-p-cymene)ruthenate(II)
por: Wu, Fang-Hui, et al.
Publicado: (2009)

Cannot write session to /tmp/vufind_sessions/sess_bjfjukkk3rn10k241ia9dd6mlf