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Mesoionic Imines (MIIs): Strong Donors and Versatile Ligands for Transition Metals and Main Group Substrates

We report the synthesis and the reactivity of 1,2,3‐triazolin‐5‐imine type mesoionic imines (MIIs). The MIIs are accessible by a base‐mediated cycloaddition between a substituted acetonitrile and an aromatic azide, methylation by established routes and subsequent deprotonation. C=O‐stretching freque...

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Detalles Bibliográficos
Autores principales: Rudolf, Richard, Neuman, Nicolás I., Walter, Robert R. M., Ringenberg, Mark. R., Sarkar, Biprajit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322014/
https://www.ncbi.nlm.nih.gov/pubmed/35286004
http://dx.doi.org/10.1002/anie.202200653