Cargando…
Mesoionic Imines (MIIs): Strong Donors and Versatile Ligands for Transition Metals and Main Group Substrates
We report the synthesis and the reactivity of 1,2,3‐triazolin‐5‐imine type mesoionic imines (MIIs). The MIIs are accessible by a base‐mediated cycloaddition between a substituted acetonitrile and an aromatic azide, methylation by established routes and subsequent deprotonation. C=O‐stretching freque...
Autores principales: | Rudolf, Richard, Neuman, Nicolás I., Walter, Robert R. M., Ringenberg, Mark. R., Sarkar, Biprajit |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322014/ https://www.ncbi.nlm.nih.gov/pubmed/35286004 http://dx.doi.org/10.1002/anie.202200653 |
Ejemplares similares
-
Chemistry of Compounds Based on 1,2,3-Triazolylidene-Type
Mesoionic Carbenes
por: Maity, Ramananda, et al.
Publicado: (2021) -
Directed Design of a Au(I) Complex with a Reduced Mesoionic Carbene Radical Ligand: Insights from 1,2,3‐Triazolylidene Selenium Adducts and Extensive Electrochemical Investigations
por: Beerhues, Julia, et al.
Publicado: (2021) -
Impact of
Bidentate Pyridyl-Mesoionic Carbene Ligands:
Structural, (Spectro)Electrochemical, Photophysical, and Theoretical
Investigations on Ruthenium(II) Complexes
por: Bens, Tobias, et al.
Publicado: (2023) -
Copper(I) Complexes of Mesoionic Carbene: Structural Characterization and Catalytic Hydrosilylation Reactions
por: Hohloch, Stephan, et al.
Publicado: (2015) -
Isomerization Reactions in Anionic Mesoionic Carbene‐Borates and Control of Properties and Reactivities in the Resulting Co(II) Complexes through Agostic Interactions
por: Stubbe, Jessica, et al.
Publicado: (2020)