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Reactivity of Diphenylberyllium as a Brønsted Base and Its Synthetic Application

Diphenylberyllium [Be(3)Ph(6)] is shown here to react cleanly as a Brønsted base with a vast variety of protic compounds. Through the addition of the simple molecules tBuOH, HNPh(2) and HPPh(2), as well as the more complex 1,3‐bis‐(2,6‐diisopropylphenyl)imidazolinium chloride, one or two phenyl grou...

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Detalles Bibliográficos
Autores principales: Thomas‐Hargreaves, Lewis R., Berthold, Chantsalmaa, Augustinov, William, Müller, Matthias, Ivlev, Sergei I., Buchner, Magnus R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9322039/
https://www.ncbi.nlm.nih.gov/pubmed/35389541
http://dx.doi.org/10.1002/chem.202200851