Microwave Irradiation as a Powerful Tool for the Preparation of n-Type Benzotriazole Semiconductors with Applications in Organic Field-Effect Transistors

In this work, as an equivocal proof of the potential of microwave irradiation in organic synthesis, a complex pyrazine-decorated benzotriazole derivative that is challenging to prepare under conventional conditions has been obtained upon microwave irradiation, thus efficiently improving the process...

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Autores principales: Torres-Moya, Iván, Harbuzaru, Alexandra, Donoso, Beatriz, Prieto, Pilar, Ponce Ortiz, Rocío, Díaz-Ortiz, Ángel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323175/
https://www.ncbi.nlm.nih.gov/pubmed/35889212
http://dx.doi.org/10.3390/molecules27144340
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author Torres-Moya, Iván
Harbuzaru, Alexandra
Donoso, Beatriz
Prieto, Pilar
Ponce Ortiz, Rocío
Díaz-Ortiz, Ángel
author_facet Torres-Moya, Iván
Harbuzaru, Alexandra
Donoso, Beatriz
Prieto, Pilar
Ponce Ortiz, Rocío
Díaz-Ortiz, Ángel
author_sort Torres-Moya, Iván
collection PubMed
description In this work, as an equivocal proof of the potential of microwave irradiation in organic synthesis, a complex pyrazine-decorated benzotriazole derivative that is challenging to prepare under conventional conditions has been obtained upon microwave irradiation, thus efficiently improving the process and yields, dramatically decreasing the reaction times and resulting in an environmentally friendly synthetic procedure. In addition, this useful derivative could be applied in organic electronics, specifically in organic field-effect transistors (OFETs), exhibiting the highest electron mobilities reported to date for benzotriazole discrete molecules, of around 10(−2) cm(2)V(−1)s(−1).
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spelling pubmed-93231752022-07-27 Microwave Irradiation as a Powerful Tool for the Preparation of n-Type Benzotriazole Semiconductors with Applications in Organic Field-Effect Transistors Torres-Moya, Iván Harbuzaru, Alexandra Donoso, Beatriz Prieto, Pilar Ponce Ortiz, Rocío Díaz-Ortiz, Ángel Molecules Article In this work, as an equivocal proof of the potential of microwave irradiation in organic synthesis, a complex pyrazine-decorated benzotriazole derivative that is challenging to prepare under conventional conditions has been obtained upon microwave irradiation, thus efficiently improving the process and yields, dramatically decreasing the reaction times and resulting in an environmentally friendly synthetic procedure. In addition, this useful derivative could be applied in organic electronics, specifically in organic field-effect transistors (OFETs), exhibiting the highest electron mobilities reported to date for benzotriazole discrete molecules, of around 10(−2) cm(2)V(−1)s(−1). MDPI 2022-07-06 /pmc/articles/PMC9323175/ /pubmed/35889212 http://dx.doi.org/10.3390/molecules27144340 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Torres-Moya, Iván
Harbuzaru, Alexandra
Donoso, Beatriz
Prieto, Pilar
Ponce Ortiz, Rocío
Díaz-Ortiz, Ángel
Microwave Irradiation as a Powerful Tool for the Preparation of n-Type Benzotriazole Semiconductors with Applications in Organic Field-Effect Transistors
title Microwave Irradiation as a Powerful Tool for the Preparation of n-Type Benzotriazole Semiconductors with Applications in Organic Field-Effect Transistors
title_full Microwave Irradiation as a Powerful Tool for the Preparation of n-Type Benzotriazole Semiconductors with Applications in Organic Field-Effect Transistors
title_fullStr Microwave Irradiation as a Powerful Tool for the Preparation of n-Type Benzotriazole Semiconductors with Applications in Organic Field-Effect Transistors
title_full_unstemmed Microwave Irradiation as a Powerful Tool for the Preparation of n-Type Benzotriazole Semiconductors with Applications in Organic Field-Effect Transistors
title_short Microwave Irradiation as a Powerful Tool for the Preparation of n-Type Benzotriazole Semiconductors with Applications in Organic Field-Effect Transistors
title_sort microwave irradiation as a powerful tool for the preparation of n-type benzotriazole semiconductors with applications in organic field-effect transistors
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323175/
https://www.ncbi.nlm.nih.gov/pubmed/35889212
http://dx.doi.org/10.3390/molecules27144340
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