Nitriles with High Gas-Phase Basicity—Part II Transmission of the Push–Pull Effect through Methylenecyclopropene and Cyclopropenimine Scaffolds Intercalated between Different Electron Donor(s) and the Cyano N-Protonation Site

This work extends our earlier quantum chemical studies on the gas-phase basicity of very strong N-bases to two series of nitriles containing the methylenecyclopropene and cyclopropenimine scaffolds with dissymmetrical substitution by one or two electron-donating substituents such as Me, NR(2), N=C (...

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Detalles Bibliográficos
Autores principales: Raczyńska, Ewa D., Gal, Jean-François, Maria, Pierre-Charles, Sakhawat, Ghulam Sakhi, Fahim, Mohammad Qasem, Saeidian, Hamid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323925/
https://www.ncbi.nlm.nih.gov/pubmed/35889241
http://dx.doi.org/10.3390/molecules27144370

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9323925/
https://www.ncbi.nlm.nih.gov/pubmed/35889241
http://dx.doi.org/10.3390/molecules27144370

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