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Discrete, Cationic Palladium(II)‐Oxo Clusters via f‐Metal Ion Incorporation and their Macrocyclic Host‐Guest Interactions with Sulfonatocalixarenes
We report on the discovery of the first two examples of cationic palladium(II)‐oxo clusters (POCs) containing f‐metal ions, [Pd(II) (6)O(12)M(8){(CH(3))(2)AsO(2)}(16)(H(2)O)(8)](4+) (M=Ce(IV), Th(IV)), and their physicochemical characterization in the solid state, in solution and in the gas phase. T...
Autores principales: | , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9324968/ https://www.ncbi.nlm.nih.gov/pubmed/35384204 http://dx.doi.org/10.1002/anie.202203114 |