Cargando…

Bonding in a Crystalline Tri‐Thorium Cluster: Not σ‐Aromatic But Still Unique

Very recently, Boronski et al. reported the first thorium–thorium bond in a crystalline cluster prepared under normal experimental conditions. By using a range of experimental techniques and computational models, the authors found that the isolated actinide cluster contains at its heart two paired e...

Descripción completa

Detalles Bibliográficos
Autor principal:	Szczepanik, Dariusz W.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9325075/ https://www.ncbi.nlm.nih.gov/pubmed/35426215 http://dx.doi.org/10.1002/anie.202204337

Ejemplares similares

On the Bonding Nature in the Crystalline Tri‐Thorium Cluster: Core‐Shell Syngenetic σ‐Aromaticity
por: Lin, Xuhui, et al.
Publicado: (2022)

The curious case of the crystalline tri-thorium cluster: cyclic delocalization without aromatic stabilization?
por: Szczepanik, Dariusz W.
Publicado: (2023)

Multiple local σ-aromaticity of nonagermanide clusters
por: Tkachenko, Nikolay V., et al.
Publicado: (2019)

σ-Aromaticity in planar pentacoordinate aluminium and gallium clusters
por: Kalita, Amlan J., et al.
Publicado: (2022)

Characterization of the Effects of Ligands on Bonding and σ-Aromaticity of Small Pt Nanoclusters
por: Reid, Samantha, et al.
Publicado: (2023)

A double bond with weak σ- and strong π-interactions is still a double bond
por: Foroutan-Nejad, Cina
Publicado: (2021)

Reply to: “A double bond with weak σ- and strong π-interactions is still a double bond”
por: Kyushin, Soichiro, et al.
Publicado: (2021)

The Origin of the σ‐Hole in Halogen Atoms: a Valence Bond Perspective
por: Franchini, Davide, et al.
Publicado: (2020)

Chemical Bonding and σ-Aromaticity in Charged Molecular Alloys: [Pd(2)As(14)](4−) and [Au(2)Sb(14)](4−) Clusters
por: You, Xue-Rui, et al.
Publicado: (2017)

Alternative σ(I)/anti-σ(I) factors represent a unique form of bacterial σ/anti-σ complex
por: Wei, Zhen, et al.
Publicado: (2019)

Electron Delocalization in Planar Metallacycles: Hückel or Möbius Aromatic?
por: Szczepanik, Dariusz W., et al.
Publicado: (2019)

Searching for double σ- and π-aromaticity in borazine derivatives
por: Pino-Rios, Ricardo, et al.
Publicado: (2020)

Thorium–ligand multiple bonds via reductive deprotection of a trityl group
por: Smiles, Danil E., et al.
Publicado: (2015)

Chemical structure and bonding in a thorium(iii)–aluminum heterobimetallic complex
por: Altman, Alison B., et al.
Publicado: (2018)

Selective C-N σ Bond Cleavage in Azetidinyl Amides under Transition Metal-Free Conditions
por: Li, Hengzhao, et al.
Publicado: (2019)

A–X⋯σ Interactions—Halogen Bonds with σ-Electrons as the Lewis Base Centre
por: Grabowski, Sławomir J.
Publicado: (2021)

Mesothorium, Thorium X, and Thorium Emanation, and Their Therapeutic Use
por: Turner, Dawson
Publicado: (1912)

Metathesis by Partner Interchange in σ‐Bond Ligands: Expanding Applications of the σ‐CAM Mechanism
por: Perutz, Robin N., et al.
Publicado: (2021)

ETS-NOCV description of σ-hole bonding
por: Dyduch, Karol, et al.
Publicado: (2012)

Le thorium
por: E.D.F - Division Information sur L'Energie. Paris, France.
Publicado: (1997)

Thorium for Pyelography
Publicado: (1916)

Boron-Based Inverse Sandwich V(2)B(7)(−) Cluster: Double π/σ Aromaticity, Metal–Metal Bonding, and Chemical Analogy to Planar Hypercoordinate Molecular Wheels
por: Han, Peng-Fei, et al.
Publicado: (2023)

Aromatic Nanosandwich Obtained by σ-Dimerization of a Nanographenoid π-Radical
por: Moshniaha, Liliia, et al.
Publicado: (2020)

Insights into the Topology and the Formation of a Genuine ppσ Bond: Experimental and Computed Electron Densities in Monoanionic Trichlorine [Cl(3)](−)
por: Keil, Helena, et al.
Publicado: (2020)

The σ enigma: Bacterial σ factors, archaeal TFB and eukaryotic TFIIB are homologs
por: Burton, Samuel P, et al.
Publicado: (2014)

A diradical based on odd-electron σ-bonds
por: Yang, Wenbang, et al.
Publicado: (2020)

Ab Initio Calculations on the Ground and Excited Electronic States of Thorium–Ammonia, Thorium–Aza-Crown, and Thorium–Crown Ether Complexes
por: Lu, Zhongyuan, et al.
Publicado: (2023)

Activation of Aromatic C−F Bonds by a N‐Heterocyclic Olefin (NHO)
por: Mandal, Debdeep, et al.
Publicado: (2020)

Covalent bond shortening and distortion induced by pressurization of thorium, uranium, and neptunium tetrakis aryloxides
por: Shephard, Jacob J., et al.
Publicado: (2022)

Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
por: Wildman, Elizabeth P., et al.
Publicado: (2016)

Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
por: Du, Jingzhen, et al.
Publicado: (2019)

Thorium production technology
por: Cuthbert, Frederick Leicester, 1913-
Publicado: (1958)

Thorium production technology
por: Cuthbert, F L
Publicado: (1958)

Thorium Fuel cycle
por: Kadi, Yacine
Publicado: (2013)

Thorium-Reactor Physics
por: Cywinski, Robert
Publicado: (2013)

The Japanese Thorium Programme
por: Sasa, Toshinobu
Publicado: (2013)

Thorium Energy for the World
por: Revol, Jean-Pierre, et al.
Publicado: (2016)

Concomitant Carboxylate and Oxalate Formation From the Activation of CO(2) by a Thorium(III) Complex
por: Formanuik, Alasdair, et al.
Publicado: (2016)

Utilizing the σ-complex stability for quantifying reactivity in nucleophilic substitution of aromatic fluorides
por: Liljenberg, Magnus, et al.
Publicado: (2013)

Aminoboration: Addition of B–N σ Bonds across C–C π Bonds
por: Chong, Eugene, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_5kbfpu9t24h8lsk4f5bt8gefed