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Taming of the DIBAL Promoted Debenzylation of α‐Cyclodextrin. Kinetics, Substituent Effects and Efficient Synthesis of Lings Tetrol

The kinetics of the reaction of perbenzyl α‐cyclodextrin was studied varying the concentration of DIBAL and substrate, and the temperature. The initial debenzylation was found to be 1(st) order in substrate and follow the relationship 0.0675+0.179[DIBAL](2) with respect to the concentration of DIBAL...

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Detalles Bibliográficos
Autores principales: Bols, Mikael, Friis, Victor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9325365/
https://www.ncbi.nlm.nih.gov/pubmed/35384086
http://dx.doi.org/10.1002/chem.202200564