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Nonacethrene Unchained: A Cascade to Chiral Contorted Conjugated Hydrocarbon with Two sp(3)-Defects
[Image: see text] We demonstrate that structurally complex carbon nanostructures can be achieved via a synthetic approach that capitalizes on a π-radical reaction cascade. The cascade is triggered by oxidation of a dihydro precursor of helical diradicaloid nonacethrene to give a chiral contorted pol...
Autores principales: | Čavlović, Daniel, Häussinger, Daniel, Blacque, Olivier, Ravat, Prince, Juríček, Michal |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9326821/ https://www.ncbi.nlm.nih.gov/pubmed/35911448 http://dx.doi.org/10.1021/jacsau.2c00190 |
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