Assessment of the Crystallization Process of CaO–Al(2)O(3)–SiO(2) Glass Probed with Tb(3+) Luminescence

[Image: see text] The ratio of the intensity of Tb(3+) fluorescence at 543 nm because of an electric dipole transition ((5)D(4)–(7)F(5)) relative to that at 437 nm due to a magnetic dipole transition ((5)D(3)–(7)F(4)) was determined to be proportional to the amount of metastable CaAl(2)Si(2)O(8) cry...

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Autores principales: Machida, Shingo, Yamaguchi, Takuma, Emori, Naoki, Katsumata, Ken-ichi, Maeda, Kei, Yasumori, Atsuo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9326970/
https://www.ncbi.nlm.nih.gov/pubmed/35830547
http://dx.doi.org/10.1021/acs.inorgchem.2c01950
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author Machida, Shingo
Yamaguchi, Takuma
Emori, Naoki
Katsumata, Ken-ichi
Maeda, Kei
Yasumori, Atsuo
author_facet Machida, Shingo
Yamaguchi, Takuma
Emori, Naoki
Katsumata, Ken-ichi
Maeda, Kei
Yasumori, Atsuo
author_sort Machida, Shingo
collection PubMed
description [Image: see text] The ratio of the intensity of Tb(3+) fluorescence at 543 nm because of an electric dipole transition ((5)D(4)–(7)F(5)) relative to that at 437 nm due to a magnetic dipole transition ((5)D(3)–(7)F(4)) was determined to be proportional to the amount of metastable CaAl(2)Si(2)O(8) crystals precipitated in CaO–Al(2)O(3)–SiO(2) glass. The present results indicate that Tb(3+) luminescence can be used as a probe to evaluate the crystallization of glass.
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spelling pubmed-93269702022-07-28 Assessment of the Crystallization Process of CaO–Al(2)O(3)–SiO(2) Glass Probed with Tb(3+) Luminescence Machida, Shingo Yamaguchi, Takuma Emori, Naoki Katsumata, Ken-ichi Maeda, Kei Yasumori, Atsuo Inorg Chem [Image: see text] The ratio of the intensity of Tb(3+) fluorescence at 543 nm because of an electric dipole transition ((5)D(4)–(7)F(5)) relative to that at 437 nm due to a magnetic dipole transition ((5)D(3)–(7)F(4)) was determined to be proportional to the amount of metastable CaAl(2)Si(2)O(8) crystals precipitated in CaO–Al(2)O(3)–SiO(2) glass. The present results indicate that Tb(3+) luminescence can be used as a probe to evaluate the crystallization of glass. American Chemical Society 2022-07-13 2022-07-25 /pmc/articles/PMC9326970/ /pubmed/35830547 http://dx.doi.org/10.1021/acs.inorgchem.2c01950 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Machida, Shingo
Yamaguchi, Takuma
Emori, Naoki
Katsumata, Ken-ichi
Maeda, Kei
Yasumori, Atsuo
Assessment of the Crystallization Process of CaO–Al(2)O(3)–SiO(2) Glass Probed with Tb(3+) Luminescence
title Assessment of the Crystallization Process of CaO–Al(2)O(3)–SiO(2) Glass Probed with Tb(3+) Luminescence
title_full Assessment of the Crystallization Process of CaO–Al(2)O(3)–SiO(2) Glass Probed with Tb(3+) Luminescence
title_fullStr Assessment of the Crystallization Process of CaO–Al(2)O(3)–SiO(2) Glass Probed with Tb(3+) Luminescence
title_full_unstemmed Assessment of the Crystallization Process of CaO–Al(2)O(3)–SiO(2) Glass Probed with Tb(3+) Luminescence
title_short Assessment of the Crystallization Process of CaO–Al(2)O(3)–SiO(2) Glass Probed with Tb(3+) Luminescence
title_sort assessment of the crystallization process of cao–al(2)o(3)–sio(2) glass probed with tb(3+) luminescence
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9326970/
https://www.ncbi.nlm.nih.gov/pubmed/35830547
http://dx.doi.org/10.1021/acs.inorgchem.2c01950
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