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Experimental Study on Profile Control of Polymer and Weak Gel Molecules in Porous Media

Weak gel is a gel system formed by the mixing and crosslinking of a low-concentration polymer and a slow-release crosslinker. It can be used for profile control in deep reservoir, but its effect is greatly affected by mechanical shearing. Currently, the shearing effect on weak gel is mainly studied...

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Autores principales: Li, Xuanran, Wei, Jing, Zhao, Lun, Ni, Jun, Fu, Libing, Wang, Jincai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9330906/
https://www.ncbi.nlm.nih.gov/pubmed/35892726
http://dx.doi.org/10.3390/gels8080467
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author Li, Xuanran
Wei, Jing
Zhao, Lun
Ni, Jun
Fu, Libing
Wang, Jincai
author_facet Li, Xuanran
Wei, Jing
Zhao, Lun
Ni, Jun
Fu, Libing
Wang, Jincai
author_sort Li, Xuanran
collection PubMed
description Weak gel is a gel system formed by the mixing and crosslinking of a low-concentration polymer and a slow-release crosslinker. It can be used for profile control in deep reservoir, but its effect is greatly affected by mechanical shearing. Currently, the shearing effect on weak gel is mainly studied by way of mechanical stirring, while the effect of porous media shear on weak gel molecules and properties has been rarely discussed. In this paper, polymer solution, aluminum gel and phenolic gel were prepared. The molecular coil size, viscoelastic modulus and microscopic aggregation morphology in water solution of three systems before and after core shearing were investigated, and the injection performance of the three systems in cores with different permeabilities was tested by physical simulation experiments. The study results show that at equivalent permeability, the system with a larger equivalent sphere diameter of molecular coil is more seriously sheared and suffers greater viscosity loss. In the core with permeability of 1.0 D, polymer solution remains as the aggregation, while phenolic gel and aluminum gel cannot form network aggregations and they are inferior to polymer solution in migration capacity in the mid-deep part of the core. In the core with permeability of 1–5.8 D, the polymer solution remains as a Newtonian fluid, while phenolic gel and aluminum gel become purely viscous non-Newtonian fluids. The elastic modulus of aluminum gel and phenolic gel is four times more than that of a polymer. In the core with permeability higher than 8.5 D, aluminum gel and phenolic gel migrate with less effect by core shearing, and their profile control capacity in deep reservoir is higher than that of the polymer. In the core with permeability lower than 8.5 D, because the monomolecular activity of weak gels becomes poor, they migrate in porous media with more effect by core shearing, and their profile control and oil displacement capacity in deep reservoir is lower than that of the polymer.
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spelling pubmed-93309062022-07-29 Experimental Study on Profile Control of Polymer and Weak Gel Molecules in Porous Media Li, Xuanran Wei, Jing Zhao, Lun Ni, Jun Fu, Libing Wang, Jincai Gels Article Weak gel is a gel system formed by the mixing and crosslinking of a low-concentration polymer and a slow-release crosslinker. It can be used for profile control in deep reservoir, but its effect is greatly affected by mechanical shearing. Currently, the shearing effect on weak gel is mainly studied by way of mechanical stirring, while the effect of porous media shear on weak gel molecules and properties has been rarely discussed. In this paper, polymer solution, aluminum gel and phenolic gel were prepared. The molecular coil size, viscoelastic modulus and microscopic aggregation morphology in water solution of three systems before and after core shearing were investigated, and the injection performance of the three systems in cores with different permeabilities was tested by physical simulation experiments. The study results show that at equivalent permeability, the system with a larger equivalent sphere diameter of molecular coil is more seriously sheared and suffers greater viscosity loss. In the core with permeability of 1.0 D, polymer solution remains as the aggregation, while phenolic gel and aluminum gel cannot form network aggregations and they are inferior to polymer solution in migration capacity in the mid-deep part of the core. In the core with permeability of 1–5.8 D, the polymer solution remains as a Newtonian fluid, while phenolic gel and aluminum gel become purely viscous non-Newtonian fluids. The elastic modulus of aluminum gel and phenolic gel is four times more than that of a polymer. In the core with permeability higher than 8.5 D, aluminum gel and phenolic gel migrate with less effect by core shearing, and their profile control capacity in deep reservoir is higher than that of the polymer. In the core with permeability lower than 8.5 D, because the monomolecular activity of weak gels becomes poor, they migrate in porous media with more effect by core shearing, and their profile control and oil displacement capacity in deep reservoir is lower than that of the polymer. MDPI 2022-07-26 /pmc/articles/PMC9330906/ /pubmed/35892726 http://dx.doi.org/10.3390/gels8080467 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Li, Xuanran
Wei, Jing
Zhao, Lun
Ni, Jun
Fu, Libing
Wang, Jincai
Experimental Study on Profile Control of Polymer and Weak Gel Molecules in Porous Media
title Experimental Study on Profile Control of Polymer and Weak Gel Molecules in Porous Media
title_full Experimental Study on Profile Control of Polymer and Weak Gel Molecules in Porous Media
title_fullStr Experimental Study on Profile Control of Polymer and Weak Gel Molecules in Porous Media
title_full_unstemmed Experimental Study on Profile Control of Polymer and Weak Gel Molecules in Porous Media
title_short Experimental Study on Profile Control of Polymer and Weak Gel Molecules in Porous Media
title_sort experimental study on profile control of polymer and weak gel molecules in porous media
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9330906/
https://www.ncbi.nlm.nih.gov/pubmed/35892726
http://dx.doi.org/10.3390/gels8080467
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