Electronically Asynchronous Transition States for C–N Bond Formation by Electrophilic [Co(III)(TAML)]-Nitrene Radical Complexes Involving Substrate-to-Ligand Single-Electron Transfer and a Cobalt-Centered Spin Shuttle

[Image: see text] The oxidation state of the redox noninnocent tetra-amido macrocyclic ligand (TAML) scaffold was recently shown to affect the formation of nitrene radical species on cobalt(III) upon reaction with PhI=NNs [ N. P. van Leest; J. Am. Chem. Soc.2020, 142, 552−56331846578]. For the neutr...

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Detalles Bibliográficos
Autores principales: van Leest, Nicolaas P., Tepaske, Martijn A., Venderbosch, Bas, Oudsen, Jean-Pierre H., Tromp, Moniek, van der Vlugt, Jarl Ivar, de Bruin, Bas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9333348/
https://www.ncbi.nlm.nih.gov/pubmed/35912398
http://dx.doi.org/10.1021/acscatal.0c01343

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