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A bis(silylene)pyridine pincer ligand can stabilize mononuclear manganese(0) complexes: facile access to isolable analogues of the elusive d(7)-Mn(CO)(5) radical

Using the potentially tridentate N,N′-bis(N-heterocyclic silylene)pyridine [SiNSi] pincer-type ligand, 2,6-N,N′-diethyl-bis[N,N′-di-tert-butyl(phenylamidinato)silylene] diaminopyridine, led to the first isolable bis(silylene)pyridine-stabilized manganese(0) complex, {κ(3)-[SiNSi]Mn(dmpe)} 4 (dmpe =...

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Detalles Bibliográficos
Autores principales:	Kalra, Shweta, Pividori, Daniel, Fehn, Dominik, Dai, Chenshu, Dong, Shicheng, Yao, Shenglai, Zhu, Jun, Meyer, Karsten, Driess, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9337724/ https://www.ncbi.nlm.nih.gov/pubmed/35974753 http://dx.doi.org/10.1039/d2sc03352f

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