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Unexpected steric hindrance failure in the gas phase F(−) + (CH(3))(3)CI S(N)2 reaction

Base-induced elimination (E2) and bimolecular nucleophilic substitution (S(N)2) reactions are of significant importance in physical organic chemistry. The textbook example of the retardation of S(N)2 reactivity by bulky alkyl substitution is widely accepted based on the static analysis of molecular...

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Detalles Bibliográficos
Autores principales:	Lu, Xiaoxiao, Shang, Chenyao, Li, Lulu, Chen, Rongjun, Fu, Bina, Xu, Xin, Zhang, Dong H.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9338938/ https://www.ncbi.nlm.nih.gov/pubmed/35907925 http://dx.doi.org/10.1038/s41467-022-32191-6

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