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Inside or outside the box? Effect of substrate location on coordination-cage based catalysis

In this work we compare and contrast the hydrolysis of two different aromatic esters using an octanuclear cubic Co(8) coordination cage host as the catalyst. Diacetyl fluorescein (DAF) is too large to bind inside the cage cavity, but in aqueous solution it interacts with the exterior surface of the...

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Detalles Bibliográficos
Autores principales:	Solea, Atena B., Sudittapong, Burin, Taylor, Christopher G. P., Ward, Michael D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9344580/ https://www.ncbi.nlm.nih.gov/pubmed/35791857 http://dx.doi.org/10.1039/d2dt01713j

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