Ring-opening of non-activated aziridines with [(11)C]CO(2)via novel ionic liquids

Novel ionic liquids based on DBU and DBN halide salts were developed as a catalytic system for ring-opening of non-activated aziridines with [(11)C]CO(2). The ability of ionic liquids to activate aziridines represents a simple methodology for the synthesis of (11)C-carbamates and can be extended for...

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Detalles Bibliográficos
Autores principales: Lindberg, Anton, Vasdev, Neil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9345297/
https://www.ncbi.nlm.nih.gov/pubmed/35975081
http://dx.doi.org/10.1039/d2ra03966d
Descripción
Sumario:Novel ionic liquids based on DBU and DBN halide salts were developed as a catalytic system for ring-opening of non-activated aziridines with [(11)C]CO(2). The ability of ionic liquids to activate aziridines represents a simple methodology for the synthesis of (11)C-carbamates and can be extended for CO(2)-fixation in organic and radiochemistry.

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