Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction

[Image: see text] Herein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to th...

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Autores principales: Day, Craig S., Do, Cuong Dat, Odena, Carlota, Benet-Buchholz, Jordi, Xu, Liang, Foroutan-Nejad, Cina, Hopmann, Kathrin H., Martin, Ruben
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9345648/
https://www.ncbi.nlm.nih.gov/pubmed/35830190
http://dx.doi.org/10.1021/jacs.2c01807
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author Day, Craig S.
Do, Cuong Dat
Odena, Carlota
Benet-Buchholz, Jordi
Xu, Liang
Foroutan-Nejad, Cina
Hopmann, Kathrin H.
Martin, Ruben
author_facet Day, Craig S.
Do, Cuong Dat
Odena, Carlota
Benet-Buchholz, Jordi
Xu, Liang
Foroutan-Nejad, Cina
Hopmann, Kathrin H.
Martin, Ruben
author_sort Day, Craig S.
collection PubMed
description [Image: see text] Herein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to their high solubility, modular redox potentials, and formation of insoluble, non-coordinating byproducts. The applicability of these reductants is showcased by accessing low-valent (bipy)(2)Ni(0) species that are challenging to access otherwise.
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spelling pubmed-93456482022-08-03 Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction Day, Craig S. Do, Cuong Dat Odena, Carlota Benet-Buchholz, Jordi Xu, Liang Foroutan-Nejad, Cina Hopmann, Kathrin H. Martin, Ruben J Am Chem Soc [Image: see text] Herein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to their high solubility, modular redox potentials, and formation of insoluble, non-coordinating byproducts. The applicability of these reductants is showcased by accessing low-valent (bipy)(2)Ni(0) species that are challenging to access otherwise. American Chemical Society 2022-07-13 2022-07-27 /pmc/articles/PMC9345648/ /pubmed/35830190 http://dx.doi.org/10.1021/jacs.2c01807 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Day, Craig S.
Do, Cuong Dat
Odena, Carlota
Benet-Buchholz, Jordi
Xu, Liang
Foroutan-Nejad, Cina
Hopmann, Kathrin H.
Martin, Ruben
Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction
title Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction
title_full Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction
title_fullStr Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction
title_full_unstemmed Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction
title_short Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction
title_sort room-temperature-stable magnesium electride via ni(ii) reduction
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9345648/
https://www.ncbi.nlm.nih.gov/pubmed/35830190
http://dx.doi.org/10.1021/jacs.2c01807
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