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A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture
Carbon capture and sequestration reduces carbon dioxide emissions and is critical in accomplishing carbon neutrality targets. Here, we demonstrate new sustainable, solid-state, polyamine-appended, cyanuric acid–stabilized melamine nanoporous networks (MNNs) via dynamic combinatorial chemistry (DCC)...
Autores principales: | , , , , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Association for the Advancement of Science
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348791/ https://www.ncbi.nlm.nih.gov/pubmed/35921416 http://dx.doi.org/10.1126/sciadv.abo6849 |
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author | Mao, Haiyan Tang, Jing Day, Gregory S. Peng, Yucan Wang, Haoze Xiao, Xin Yang, Yufei Jiang, Yuanwen Chen, Shuo Halat, David M. Lund, Alicia Lv, Xudong Zhang, Wenbo Yang, Chongqing Lin, Zhou Zhou, Hong-Cai Pines, Alexander Cui, Yi Reimer, Jeffrey A. |
author_facet | Mao, Haiyan Tang, Jing Day, Gregory S. Peng, Yucan Wang, Haoze Xiao, Xin Yang, Yufei Jiang, Yuanwen Chen, Shuo Halat, David M. Lund, Alicia Lv, Xudong Zhang, Wenbo Yang, Chongqing Lin, Zhou Zhou, Hong-Cai Pines, Alexander Cui, Yi Reimer, Jeffrey A. |
author_sort | Mao, Haiyan |
collection | PubMed |
description | Carbon capture and sequestration reduces carbon dioxide emissions and is critical in accomplishing carbon neutrality targets. Here, we demonstrate new sustainable, solid-state, polyamine-appended, cyanuric acid–stabilized melamine nanoporous networks (MNNs) via dynamic combinatorial chemistry (DCC) at the kilogram scale toward effective and high-capacity carbon dioxide capture. Polyamine-appended MNNs reaction mechanisms with carbon dioxide were elucidated with double-level DCC where two-dimensional heteronuclear chemical shift correlation nuclear magnetic resonance spectroscopy was performed to demonstrate the interatomic interactions. We distinguished ammonium carbamate pairs and a mix of ammonium carbamate and carbamic acid during carbon dioxide chemisorption. The coordination of polyamine and cyanuric acid modification endows MNNs with high adsorption capacity (1.82 millimoles per gram at 1 bar), fast adsorption time (less than 1 minute), low price, and extraordinary stability to cycling by flue gas. This work creates a general industrialization method toward carbon dioxide capture via DCC atomic-level design strategies. |
format | Online Article Text |
id | pubmed-9348791 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | American Association for the Advancement of Science |
record_format | MEDLINE/PubMed |
spelling | pubmed-93487912022-08-18 A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture Mao, Haiyan Tang, Jing Day, Gregory S. Peng, Yucan Wang, Haoze Xiao, Xin Yang, Yufei Jiang, Yuanwen Chen, Shuo Halat, David M. Lund, Alicia Lv, Xudong Zhang, Wenbo Yang, Chongqing Lin, Zhou Zhou, Hong-Cai Pines, Alexander Cui, Yi Reimer, Jeffrey A. Sci Adv Physical and Materials Sciences Carbon capture and sequestration reduces carbon dioxide emissions and is critical in accomplishing carbon neutrality targets. Here, we demonstrate new sustainable, solid-state, polyamine-appended, cyanuric acid–stabilized melamine nanoporous networks (MNNs) via dynamic combinatorial chemistry (DCC) at the kilogram scale toward effective and high-capacity carbon dioxide capture. Polyamine-appended MNNs reaction mechanisms with carbon dioxide were elucidated with double-level DCC where two-dimensional heteronuclear chemical shift correlation nuclear magnetic resonance spectroscopy was performed to demonstrate the interatomic interactions. We distinguished ammonium carbamate pairs and a mix of ammonium carbamate and carbamic acid during carbon dioxide chemisorption. The coordination of polyamine and cyanuric acid modification endows MNNs with high adsorption capacity (1.82 millimoles per gram at 1 bar), fast adsorption time (less than 1 minute), low price, and extraordinary stability to cycling by flue gas. This work creates a general industrialization method toward carbon dioxide capture via DCC atomic-level design strategies. American Association for the Advancement of Science 2022-08-03 /pmc/articles/PMC9348791/ /pubmed/35921416 http://dx.doi.org/10.1126/sciadv.abo6849 Text en Copyright © 2022 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). https://creativecommons.org/licenses/by-nc/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license (https://creativecommons.org/licenses/by-nc/4.0/) , which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited. |
spellingShingle | Physical and Materials Sciences Mao, Haiyan Tang, Jing Day, Gregory S. Peng, Yucan Wang, Haoze Xiao, Xin Yang, Yufei Jiang, Yuanwen Chen, Shuo Halat, David M. Lund, Alicia Lv, Xudong Zhang, Wenbo Yang, Chongqing Lin, Zhou Zhou, Hong-Cai Pines, Alexander Cui, Yi Reimer, Jeffrey A. A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture |
title | A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture |
title_full | A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture |
title_fullStr | A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture |
title_full_unstemmed | A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture |
title_short | A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture |
title_sort | scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture |
topic | Physical and Materials Sciences |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348791/ https://www.ncbi.nlm.nih.gov/pubmed/35921416 http://dx.doi.org/10.1126/sciadv.abo6849 |
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