Cargando…

One-Metal/Two-Ligand for Dual Activation Tandem Catalysis: Photoinduced Cu-Catalyzed Anti-hydroboration of Alkynes

[Image: see text] A dual catalyst system based on ligand exchange of two diphosphine ligands possessing different properties in a copper complex has been devised to merge metal- and photocatalytic activation modes. This strategy has been applied to the formal anti-hydroboration of activated internal...

Descripción completa

Detalles Bibliográficos
Autores principales:	Corpas, Javier, Gomez-Mendoza, Miguel, Ramírez-Cárdenas, Jonathan, de la Peña O’Shea, Víctor A., Mauleón, Pablo, Gómez Arrayás, Ramón, Carretero, Juan C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9348838/ https://www.ncbi.nlm.nih.gov/pubmed/35786909 http://dx.doi.org/10.1021/jacs.2c05805

Ejemplares similares

Iterative Dual-Metal and Energy Transfer Catalysis Enables Stereodivergence in Alkyne Difunctionalization: Carboboration as Case Study
por: Corpas, Javier, et al.
Publicado: (2023)

Interplay between the Directing Group and Multifunctional Acetate Ligand in Pd-Catalyzed anti-Acetoxylation of Unsymmetrical Dialkyl-Substituted Alkynes
por: Corpas, Javier, et al.
Publicado: (2022)

Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes
por: Jin, Shengnan, et al.
Publicado: (2022)

Publisher Correction: Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes
por: Jin, Shengnan, et al.
Publicado: (2022)

Electrochemical Hydroboration of Alkynes
por: Aelterman, Maude, et al.
Publicado: (2021)

Solvent-free hydroboration of alkynes catalyzed by an NHC–cobalt complex
por: Bołt, Małgorzata, et al.
Publicado: (2022)

Photoinduced Palladium‐Catalyzed Dicarbofunctionalization of Terminal Alkynes
por: Yang, Zhen, et al.
Publicado: (2021)

Reaction Pathways and Redox States in α‐Selective Cobalt‐Catalyzed Hydroborations of Alkynes
por: Blasius, Clemens K., et al.
Publicado: (2020)

Palladium-catalyzed hydroboration reaction of unactivated alkynes with bis (pinacolato) diboron in water
por: Yang, Ming, et al.
Publicado: (2022)

Aluminum Amidinates: Insights into Alkyne Hydroboration
por: Hobson, Katie, et al.
Publicado: (2021)

Copper‐Photocatalyzed Hydroboration of Alkynes and Alkenes
por: Zhong, Mingbing, et al.
Publicado: (2021)

Highly Chemoselective Hydroboration of Alkynes and Nitriles Catalyzed by Group 4 Metal Amidophosphine–Borane Complexes
por: Bhattacharjee, Jayeeta, et al.
Publicado: (2020)

Combined Photoredox and Iron Catalysis for the Cyclotrimerization of Alkynes
por: Neumeier, Michael, et al.
Publicado: (2020)

Iridium‐Catalyzed Hydrochlorination and Hydrobromination of Alkynes by Shuttle Catalysis
por: Yu, Peng, et al.
Publicado: (2020)

Ligand relay catalysis for cobalt-catalyzed sequential hydrosilylation and hydrohydrazidation of terminal alkynes
por: Sun, Yufeng, et al.
Publicado: (2022)

Manganese‐Catalyzed Hydroborations with Broad Scope
por: Ghosh, Pradip, et al.
Publicado: (2021)

Hydroboration of Terminal Alkenes and trans‐1,2‐Diboration of Terminal Alkynes Catalyzed by a Manganese(I) Alkyl Complex
por: Weber, Stefan, et al.
Publicado: (2021)

A simple synthesis of surfactant-free polycrystalline CuO nanoparticles supported on carbon nanofibers for regioselective hydroboration of alkynes
por: Mohan, Balaji, et al.
Publicado: (2022)

Spectral data for the synthesis of (E)-alkenylboronic acid pinacol esters via hydroboration of alkynes
por: Gioia, Bruna, et al.
Publicado: (2020)

Rh(I)/Rh(III) catalyst-controlled divergent aryl/heteroaryl C–H bond functionalization of picolinamides with alkynes
por: Martínez, Ángel Manu, et al.
Publicado: (2015)

Grignard Reagent-Catalyzed Hydroboration of Esters, Nitriles, and Imines
por: Han, Hyun Ji, et al.
Publicado: (2023)

Photocontrolled Cobalt Catalysis for Selective Hydroboration of α,β‐Unsaturated Ketones
por: Beltran, Frédéric, et al.
Publicado: (2020)

Ligand-controlled cobalt-catalyzed regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes
por: Wu, Caizhi, et al.
Publicado: (2020)

Boric acid as a precatalyst for BH(3)-catalyzed hydroboration
por: Légaré Lavergne, Julien, et al.
Publicado: (2021)

Au(I) Catalyzed HF Transfer: Tandem Alkyne Hydrofluorination and Perfluoroarene Functionalization
por: Mulryan, Daniel, et al.
Publicado: (2022)

Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups
por: Erken, Christina, et al.
Publicado: (2018)

Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes
por: Smith, James R., et al.
Publicado: (2017)

Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set
por: Pollard, Victoria A., et al.
Publicado: (2018)

trans-Hydroboration–oxidation products in Δ(5)-steroids via a hydroboration-retro-hydroboration mechanism
por: Hilario-Martínez, J. Ciciolil, et al.
Publicado: (2020)

Reactions of an Osmium–Hexahydride Complex with 2-Butyne and 3-Hexyne and Their Performance in the Migratory Hydroboration of Aliphatic Internal Alkynes
por: Babón, Juan C., et al.
Publicado: (2022)

The directions of an external electric field control the catalysis of the hydroboration of C–O unsaturated compounds
por: Zhang, Ming-Xia, et al.
Publicado: (2019)

Redox catalysis via photoinduced electron transfer
por: Lee, Yong-Min, et al.
Publicado: (2023)

Mechanistic study of homoleptic trisamidolanthanide-catalyzed aldehyde and ketone hydroboration. Chemically non-innocent ligand participation
por: Rothbaum, Jacob O., et al.
Publicado: (2023)

Oxidant speciation and anionic ligand effects in the gold-catalyzed oxidative coupling of arenes and alkynes
por: Hofer, Manuel, et al.
Publicado: (2019)

Enantioselective Cobalt-Catalyzed Hydroboration of Fluoroalkyl-Substituted Alkenes to Access Chiral Fluoroalkylboronates
por: Hu, Ming, et al.
Publicado: (2022)

Highly selective catalytic trans-hydroboration of alkynes mediated by borenium cations and B(C(6)F(5))(3)
por: McGough, John S., et al.
Publicado: (2016)

A recyclable and reusable supported Cu(I) catalyzed azide-alkyne click polymerization
por: Wu, Haiqiang, et al.
Publicado: (2014)

Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne “click reaction”
por: Jin, Liqun, et al.
Publicado: (2015)

Multifaceted behavior of a doubly reduced arylborane in B–H-bond activation and hydroboration catalysis
por: Prey, Sven E., et al.
Publicado: (2022)

Copper-catalyzed radical trans-selective hydroboration of ynamides with N-heterocyclic carbene boranes
por: Wang, Kefeng, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_7njava467uc4ddmh3rmlcsms0j