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Chiral oxazolidines acting as transient hydroxyalkyl-functionalized N-heterocyclic carbenes: an efficient route to air stable copper and gold complexes for asymmetric catalysis

Optically pure oxazolidines were synthesized in nearly quantitative yields from chiral hydroxyalkyl-functionalized imidazolinium salts. Acting as transient chiral diamino N-heterocyclic carbenes (NHCs), these oxazolidines allowed the efficient formation of well-defined copper(i) and gold(i) hydroxya...

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Detalles Bibliográficos
Autores principales:	Pichon-Barré, Delphine, Zhang, Ziyun, Cador, Aël, Vives, Thomas, Roisnel, Thierry, Baslé, Olivier, Jarrige, Lucie, Cavallo, Luigi, Falivene, Laura, Mauduit, Marc
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9350591/ https://www.ncbi.nlm.nih.gov/pubmed/35975143 http://dx.doi.org/10.1039/d2sc02908a

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