Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation

A photo-induced C-S radical cross-coupling of aryl iodides and disulfides under transition-metal and external photosensitizer free conditions for the synthesis of aryl sulfides at room temperature has been presented, which features mild reaction conditions, broad substrate scope, high efficiency, an...

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Autores principales: Mao, Shuai, Zhao, Yahao, Luo, Zixuan, Wang, Ruizhe, Yuan, Bo, Hu, Jianping, Hu, Linghao, Zhang, San-Qi, Ye, Xiaoxing, Wang, Mingliang, Chen, Zhengkai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9360480/
https://www.ncbi.nlm.nih.gov/pubmed/35958235
http://dx.doi.org/10.3389/fchem.2022.941016
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author Mao, Shuai
Zhao, Yahao
Luo, Zixuan
Wang, Ruizhe
Yuan, Bo
Hu, Jianping
Hu, Linghao
Zhang, San-Qi
Ye, Xiaoxing
Wang, Mingliang
Chen, Zhengkai
author_facet Mao, Shuai
Zhao, Yahao
Luo, Zixuan
Wang, Ruizhe
Yuan, Bo
Hu, Jianping
Hu, Linghao
Zhang, San-Qi
Ye, Xiaoxing
Wang, Mingliang
Chen, Zhengkai
author_sort Mao, Shuai
collection PubMed
description A photo-induced C-S radical cross-coupling of aryl iodides and disulfides under transition-metal and external photosensitizer free conditions for the synthesis of aryl sulfides at room temperature has been presented, which features mild reaction conditions, broad substrate scope, high efficiency, and good functional group compatibility. The developed methodology could be readily applied to forge C-S bond in the field of pharmaceutical and material science.
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spelling pubmed-93604802022-08-10 Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation Mao, Shuai Zhao, Yahao Luo, Zixuan Wang, Ruizhe Yuan, Bo Hu, Jianping Hu, Linghao Zhang, San-Qi Ye, Xiaoxing Wang, Mingliang Chen, Zhengkai Front Chem Chemistry A photo-induced C-S radical cross-coupling of aryl iodides and disulfides under transition-metal and external photosensitizer free conditions for the synthesis of aryl sulfides at room temperature has been presented, which features mild reaction conditions, broad substrate scope, high efficiency, and good functional group compatibility. The developed methodology could be readily applied to forge C-S bond in the field of pharmaceutical and material science. Frontiers Media S.A. 2022-07-26 /pmc/articles/PMC9360480/ /pubmed/35958235 http://dx.doi.org/10.3389/fchem.2022.941016 Text en Copyright © 2022 Mao, Zhao, Luo, Wang, Yuan, Hu, Hu, Zhang, Ye, Wang and Chen. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Mao, Shuai
Zhao, Yahao
Luo, Zixuan
Wang, Ruizhe
Yuan, Bo
Hu, Jianping
Hu, Linghao
Zhang, San-Qi
Ye, Xiaoxing
Wang, Mingliang
Chen, Zhengkai
Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation
title Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation
title_full Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation
title_fullStr Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation
title_full_unstemmed Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation
title_short Metal-free photo-induced sulfidation of aryl iodide and other chalcogenation
title_sort metal-free photo-induced sulfidation of aryl iodide and other chalcogenation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9360480/
https://www.ncbi.nlm.nih.gov/pubmed/35958235
http://dx.doi.org/10.3389/fchem.2022.941016
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