Synthesis and structure of hexa­aqua­cobalt bis­(2-methyl-1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato-κO)cobalt

The title compound, (C(4)H(7)N(2))(2)[Co(H(2)O)(6)][Co(C(9)H(3)O(6))(2)(H(2)O)(4)] (1), was synthesized from cobalt(II) chloride, 1,3,5-benzene tri­carb­oxy­lic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of 1 is here reported and compared with the parent comp...

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Detalles Bibliográficos
Autores principales: Velazquez-Garcia, Jose de Jesus, Techert, Simone
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361360/
https://www.ncbi.nlm.nih.gov/pubmed/35974818
http://dx.doi.org/10.1107/S2056989022007046
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author Velazquez-Garcia, Jose de Jesus
Techert, Simone
author_facet Velazquez-Garcia, Jose de Jesus
Techert, Simone
author_sort Velazquez-Garcia, Jose de Jesus
collection PubMed
description The title compound, (C(4)H(7)N(2))(2)[Co(H(2)O)(6)][Co(C(9)H(3)O(6))(2)(H(2)O)(4)] (1), was synthesized from cobalt(II) chloride, 1,3,5-benzene tri­carb­oxy­lic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of 1 is here reported and compared with the parent complex hexa­aqua­cobalt bis­(1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato)cobalt (2).
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spelling pubmed-93613602022-08-15 Synthesis and structure of hexa­aqua­cobalt bis­(2-methyl-1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato-κO)cobalt Velazquez-Garcia, Jose de Jesus Techert, Simone Acta Crystallogr E Crystallogr Commun Research Communications The title compound, (C(4)H(7)N(2))(2)[Co(H(2)O)(6)][Co(C(9)H(3)O(6))(2)(H(2)O)(4)] (1), was synthesized from cobalt(II) chloride, 1,3,5-benzene tri­carb­oxy­lic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of 1 is here reported and compared with the parent complex hexa­aqua­cobalt bis­(1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato)cobalt (2). International Union of Crystallography 2022-07-19 /pmc/articles/PMC9361360/ /pubmed/35974818 http://dx.doi.org/10.1107/S2056989022007046 Text en © Velazquez-Garcia and Techert 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Velazquez-Garcia, Jose de Jesus
Techert, Simone
Synthesis and structure of hexa­aqua­cobalt bis­(2-methyl-1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato-κO)cobalt
title Synthesis and structure of hexa­aqua­cobalt bis­(2-methyl-1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato-κO)cobalt
title_full Synthesis and structure of hexa­aqua­cobalt bis­(2-methyl-1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato-κO)cobalt
title_fullStr Synthesis and structure of hexa­aqua­cobalt bis­(2-methyl-1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato-κO)cobalt
title_full_unstemmed Synthesis and structure of hexa­aqua­cobalt bis­(2-methyl-1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato-κO)cobalt
title_short Synthesis and structure of hexa­aqua­cobalt bis­(2-methyl-1H-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato-κO)cobalt
title_sort synthesis and structure of hexa­aqua­cobalt bis­(2-methyl-1h-imidazol-3-ium) tetra­aqua­bis­(benzene-1,3,5-tri­carboxyl­ato-κo)cobalt
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361360/
https://www.ncbi.nlm.nih.gov/pubmed/35974818
http://dx.doi.org/10.1107/S2056989022007046
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AT techertsimone synthesisandstructureofhexaaquacobaltbis2methyl1himidazol3iumtetraaquabisbenzene135tricarboxylatokocobalt

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