2-Amino-4-ferrocenyl­thia­zole

The title compound, [Fe(C(5)H(5))(C(8)H(7)N(2)S)], was synthesized by the direct reaction of acetyl­ferrocene, thio­urea and resublimed iodine. The structure shows one mol­ecule in the asymmetric unit. The amino­thia­zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is att...

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Detalles Bibliográficos
Autores principales: Anzaldo, Bertin, Sharma, Pankaj, Villamizar, Claudia. P., Gutierrez Perez, Rene, Toscano, Rubén A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361361/
https://www.ncbi.nlm.nih.gov/pubmed/35974822
http://dx.doi.org/10.1107/S2056989022007228
Descripción
Sumario:The title compound, [Fe(C(5)H(5))(C(8)H(7)N(2)S)], was synthesized by the direct reaction of acetyl­ferrocene, thio­urea and resublimed iodine. The structure shows one mol­ecule in the asymmetric unit. The amino­thia­zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex mol­ecules inter­act via inter­molecular N—H⋯N hydrogen bonds, forming a cyclic dimer which then inter­acts with other dimers through C—H⋯π inter­actions.

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