2-Amino-4-ferrocenyl­thia­zole

The title compound, [Fe(C(5)H(5))(C(8)H(7)N(2)S)], was synthesized by the direct reaction of acetyl­ferrocene, thio­urea and resublimed iodine. The structure shows one mol­ecule in the asymmetric unit. The amino­thia­zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is att...

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Detalles Bibliográficos
Autores principales: Anzaldo, Bertin, Sharma, Pankaj, Villamizar, Claudia. P., Gutierrez Perez, Rene, Toscano, Rubén A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361361/
https://www.ncbi.nlm.nih.gov/pubmed/35974822
http://dx.doi.org/10.1107/S2056989022007228
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author Anzaldo, Bertin
Sharma, Pankaj
Villamizar, Claudia. P.
Gutierrez Perez, Rene
Toscano, Rubén A.
author_facet Anzaldo, Bertin
Sharma, Pankaj
Villamizar, Claudia. P.
Gutierrez Perez, Rene
Toscano, Rubén A.
author_sort Anzaldo, Bertin
collection PubMed
description The title compound, [Fe(C(5)H(5))(C(8)H(7)N(2)S)], was synthesized by the direct reaction of acetyl­ferrocene, thio­urea and resublimed iodine. The structure shows one mol­ecule in the asymmetric unit. The amino­thia­zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex mol­ecules inter­act via inter­molecular N—H⋯N hydrogen bonds, forming a cyclic dimer which then inter­acts with other dimers through C—H⋯π inter­actions.
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spelling pubmed-93613612022-08-15 2-Amino-4-ferrocenyl­thia­zole Anzaldo, Bertin Sharma, Pankaj Villamizar, Claudia. P. Gutierrez Perez, Rene Toscano, Rubén A. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Fe(C(5)H(5))(C(8)H(7)N(2)S)], was synthesized by the direct reaction of acetyl­ferrocene, thio­urea and resublimed iodine. The structure shows one mol­ecule in the asymmetric unit. The amino­thia­zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex mol­ecules inter­act via inter­molecular N—H⋯N hydrogen bonds, forming a cyclic dimer which then inter­acts with other dimers through C—H⋯π inter­actions. International Union of Crystallography 2022-07-19 /pmc/articles/PMC9361361/ /pubmed/35974822 http://dx.doi.org/10.1107/S2056989022007228 Text en © Anzaldo et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Anzaldo, Bertin
Sharma, Pankaj
Villamizar, Claudia. P.
Gutierrez Perez, Rene
Toscano, Rubén A.
2-Amino-4-ferrocenyl­thia­zole
title 2-Amino-4-ferrocenyl­thia­zole
title_full 2-Amino-4-ferrocenyl­thia­zole
title_fullStr 2-Amino-4-ferrocenyl­thia­zole
title_full_unstemmed 2-Amino-4-ferrocenyl­thia­zole
title_short 2-Amino-4-ferrocenyl­thia­zole
title_sort 2-amino-4-ferrocenyl­thia­zole
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361361/
https://www.ncbi.nlm.nih.gov/pubmed/35974822
http://dx.doi.org/10.1107/S2056989022007228
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AT villamizarclaudiap 2amino4ferrocenylthiazole
AT gutierrezperezrene 2amino4ferrocenylthiazole
AT toscanorubena 2amino4ferrocenylthiazole

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