Crystal structure and Hirshfeld surface analysis of 2-azido-N-(4-fluoro­phen­yl)acetamide

The asymmetric unit of the title compound, C(8)H(7)FN(4)O, consists of two independent mol­ecules differing in the orientation of the azido group. Each mol­ecule forms N—H⋯O hydrogen-bonded chains along along the c-axis direction with its symmetry-related counterparts and the chains are connected by...

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Autores principales: Missioui, Mohcine, Guerrab, Walid, Alsubari, Abdulsalam, Mague, Joel T., Ramli, Youssef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361366/
https://www.ncbi.nlm.nih.gov/pubmed/35974836
http://dx.doi.org/10.1107/S2056989022006764
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author Missioui, Mohcine
Guerrab, Walid
Alsubari, Abdulsalam
Mague, Joel T.
Ramli, Youssef
author_facet Missioui, Mohcine
Guerrab, Walid
Alsubari, Abdulsalam
Mague, Joel T.
Ramli, Youssef
author_sort Missioui, Mohcine
collection PubMed
description The asymmetric unit of the title compound, C(8)H(7)FN(4)O, consists of two independent mol­ecules differing in the orientation of the azido group. Each mol­ecule forms N—H⋯O hydrogen-bonded chains along along the c-axis direction with its symmetry-related counterparts and the chains are connected by C—F⋯π(ring), C=O⋯π(ring) and slipped π-stacking inter­actions. A Hirshfeld surface analysis of these inter­actions was performed.
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spelling pubmed-93613662022-08-15 Crystal structure and Hirshfeld surface analysis of 2-azido-N-(4-fluoro­phen­yl)acetamide Missioui, Mohcine Guerrab, Walid Alsubari, Abdulsalam Mague, Joel T. Ramli, Youssef Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, C(8)H(7)FN(4)O, consists of two independent mol­ecules differing in the orientation of the azido group. Each mol­ecule forms N—H⋯O hydrogen-bonded chains along along the c-axis direction with its symmetry-related counterparts and the chains are connected by C—F⋯π(ring), C=O⋯π(ring) and slipped π-stacking inter­actions. A Hirshfeld surface analysis of these inter­actions was performed. International Union of Crystallography 2022-07-29 /pmc/articles/PMC9361366/ /pubmed/35974836 http://dx.doi.org/10.1107/S2056989022006764 Text en © Missioui et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Missioui, Mohcine
Guerrab, Walid
Alsubari, Abdulsalam
Mague, Joel T.
Ramli, Youssef
Crystal structure and Hirshfeld surface analysis of 2-azido-N-(4-fluoro­phen­yl)acetamide
title Crystal structure and Hirshfeld surface analysis of 2-azido-N-(4-fluoro­phen­yl)acetamide
title_full Crystal structure and Hirshfeld surface analysis of 2-azido-N-(4-fluoro­phen­yl)acetamide
title_fullStr Crystal structure and Hirshfeld surface analysis of 2-azido-N-(4-fluoro­phen­yl)acetamide
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 2-azido-N-(4-fluoro­phen­yl)acetamide
title_short Crystal structure and Hirshfeld surface analysis of 2-azido-N-(4-fluoro­phen­yl)acetamide
title_sort crystal structure and hirshfeld surface analysis of 2-azido-n-(4-fluoro­phen­yl)acetamide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361366/
https://www.ncbi.nlm.nih.gov/pubmed/35974836
http://dx.doi.org/10.1107/S2056989022006764
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