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Synthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxadiazole-2-thiolate
A new zinc coordination polymer with 5-phenyl-1,3,4-oxadiazole-2-thiolate, namely, catena-poly[zinc(II)-bis(μ(2)-5-phenyl-1,3,4-oxadiazole-2-thiolato)-κ(2) N (3):S;κ(2) S:N (3)], [Zn(C(8)H(5)N(2)OS)(2)]( n ), was synthesized. The single-crystal X-ray diffraction analysis shows that the polymeri...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361377/ https://www.ncbi.nlm.nih.gov/pubmed/35974814 http://dx.doi.org/10.1107/S2056989022006922 |
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author | Pirimova, Mehribon Torambetov, Batirbay Kadirova, Shakhnoza Ziyaev, Abdukhakim Gonnade, Rajesh G Ashurov, Jamshid |
author_facet | Pirimova, Mehribon Torambetov, Batirbay Kadirova, Shakhnoza Ziyaev, Abdukhakim Gonnade, Rajesh G Ashurov, Jamshid |
author_sort | Pirimova, Mehribon |
collection | PubMed |
description | A new zinc coordination polymer with 5-phenyl-1,3,4-oxadiazole-2-thiolate, namely, catena-poly[zinc(II)-bis(μ(2)-5-phenyl-1,3,4-oxadiazole-2-thiolato)-κ(2) N (3):S;κ(2) S:N (3)], [Zn(C(8)H(5)N(2)OS)(2)]( n ), was synthesized. The single-crystal X-ray diffraction analysis shows that the polymeric structure crystallizes in the centrosymmetric monoclinic C2/c space group. The Zn(II) atom is coordinated to two S and two N atoms from four crystallographically independent (L) ligands, forming zigzag chains along the [001] direction. This polymer complex forms an eight-membered [Zn–S–C–N–Zn–S–C–N] chair-like ring with two Zn(II) atoms and two ligand molecules. On the Hirshfeld surface, the largest contributions come from the short contacts such as van der Waals forces, including H⋯H, C⋯H and S⋯H. Interactions including N⋯H, O⋯H and C⋯C contacts were also observed; however, their contribution to the overall stability of the crystal lattice is minor. |
format | Online Article Text |
id | pubmed-9361377 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-93613772022-08-15 Synthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxadiazole-2-thiolate Pirimova, Mehribon Torambetov, Batirbay Kadirova, Shakhnoza Ziyaev, Abdukhakim Gonnade, Rajesh G Ashurov, Jamshid Acta Crystallogr E Crystallogr Commun Research Communications A new zinc coordination polymer with 5-phenyl-1,3,4-oxadiazole-2-thiolate, namely, catena-poly[zinc(II)-bis(μ(2)-5-phenyl-1,3,4-oxadiazole-2-thiolato)-κ(2) N (3):S;κ(2) S:N (3)], [Zn(C(8)H(5)N(2)OS)(2)]( n ), was synthesized. The single-crystal X-ray diffraction analysis shows that the polymeric structure crystallizes in the centrosymmetric monoclinic C2/c space group. The Zn(II) atom is coordinated to two S and two N atoms from four crystallographically independent (L) ligands, forming zigzag chains along the [001] direction. This polymer complex forms an eight-membered [Zn–S–C–N–Zn–S–C–N] chair-like ring with two Zn(II) atoms and two ligand molecules. On the Hirshfeld surface, the largest contributions come from the short contacts such as van der Waals forces, including H⋯H, C⋯H and S⋯H. Interactions including N⋯H, O⋯H and C⋯C contacts were also observed; however, their contribution to the overall stability of the crystal lattice is minor. International Union of Crystallography 2022-07-14 /pmc/articles/PMC9361377/ /pubmed/35974814 http://dx.doi.org/10.1107/S2056989022006922 Text en © Pirimova et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Pirimova, Mehribon Torambetov, Batirbay Kadirova, Shakhnoza Ziyaev, Abdukhakim Gonnade, Rajesh G Ashurov, Jamshid Synthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxadiazole-2-thiolate |
title | Synthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxadiazole-2-thiolate |
title_full | Synthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxadiazole-2-thiolate |
title_fullStr | Synthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxadiazole-2-thiolate |
title_full_unstemmed | Synthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxadiazole-2-thiolate |
title_short | Synthesis, crystal structure and Hirshfeld surface analysis of a zinc(II) coordination polymer of 5-phenyl-1,3,4-oxadiazole-2-thiolate |
title_sort | synthesis, crystal structure and hirshfeld surface analysis of a zinc(ii) coordination polymer of 5-phenyl-1,3,4-oxadiazole-2-thiolate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361377/ https://www.ncbi.nlm.nih.gov/pubmed/35974814 http://dx.doi.org/10.1107/S2056989022006922 |
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