Crystal structure of 8-hex­yloxy-2-[(Z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline

In the title mol­ecule, C(27)H(27)NO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the cis-vinyl bridge and the hex­yloxy chain, which adopts an all-trans conformation, resulting in transannular bifurcated intra­molecu...

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Detalles Bibliográficos
Autores principales: Liu, Xiaozhou, Wang, Lu, Feng, Ying, Cui, Deliang, Liu, Zhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361378/
https://www.ncbi.nlm.nih.gov/pubmed/35974831
http://dx.doi.org/10.1107/S2056989022006740
Descripción
Sumario:In the title mol­ecule, C(27)H(27)NO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the cis-vinyl bridge and the hex­yloxy chain, which adopts an all-trans conformation, resulting in transannular bifurcated intra­molecular C—H⋯N,O contact. The crystal structure features γ-packing of the aromatic moieties, while the parallel packing of alkyl chains resembles that of alkanes.

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