Crystal structure of 8-hex­yloxy-2-[(Z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline

In the title mol­ecule, C(27)H(27)NO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the cis-vinyl bridge and the hex­yloxy chain, which adopts an all-trans conformation, resulting in transannular bifurcated intra­molecu...

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Detalles Bibliográficos
Autores principales: Liu, Xiaozhou, Wang, Lu, Feng, Ying, Cui, Deliang, Liu, Zhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361378/
https://www.ncbi.nlm.nih.gov/pubmed/35974831
http://dx.doi.org/10.1107/S2056989022006740
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author Liu, Xiaozhou
Wang, Lu
Feng, Ying
Cui, Deliang
Liu, Zhi
author_facet Liu, Xiaozhou
Wang, Lu
Feng, Ying
Cui, Deliang
Liu, Zhi
author_sort Liu, Xiaozhou
collection PubMed
description In the title mol­ecule, C(27)H(27)NO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the cis-vinyl bridge and the hex­yloxy chain, which adopts an all-trans conformation, resulting in transannular bifurcated intra­molecular C—H⋯N,O contact. The crystal structure features γ-packing of the aromatic moieties, while the parallel packing of alkyl chains resembles that of alkanes.
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spelling pubmed-93613782022-08-15 Crystal structure of 8-hex­yloxy-2-[(Z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline Liu, Xiaozhou Wang, Lu Feng, Ying Cui, Deliang Liu, Zhi Acta Crystallogr E Crystallogr Commun Research Communications In the title mol­ecule, C(27)H(27)NO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the cis-vinyl bridge and the hex­yloxy chain, which adopts an all-trans conformation, resulting in transannular bifurcated intra­molecular C—H⋯N,O contact. The crystal structure features γ-packing of the aromatic moieties, while the parallel packing of alkyl chains resembles that of alkanes. International Union of Crystallography 2022-07-05 /pmc/articles/PMC9361378/ /pubmed/35974831 http://dx.doi.org/10.1107/S2056989022006740 Text en © Liu et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Liu, Xiaozhou
Wang, Lu
Feng, Ying
Cui, Deliang
Liu, Zhi
Crystal structure of 8-hex­yloxy-2-[(Z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline
title Crystal structure of 8-hex­yloxy-2-[(Z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline
title_full Crystal structure of 8-hex­yloxy-2-[(Z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline
title_fullStr Crystal structure of 8-hex­yloxy-2-[(Z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline
title_full_unstemmed Crystal structure of 8-hex­yloxy-2-[(Z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline
title_short Crystal structure of 8-hex­yloxy-2-[(Z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline
title_sort crystal structure of 8-hex­yloxy-2-[(z)-2-(naph­thal­en-2-yl)ethen­yl]quinoline
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361378/
https://www.ncbi.nlm.nih.gov/pubmed/35974831
http://dx.doi.org/10.1107/S2056989022006740
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