Adsorptive separation of para-xylene by nonporous adaptive crystals of phenanthrene[2]arene

In this work, we developed a new method for the preparation of phenanthrene[2]arene on a large-scale. Meanwhile, the synthetic phenanthrene[2]arene has been successfully used as nonporous adaptive crystals for the separation of para-xylene (pX) from xylene isomers. The crystal structure revealed tha...

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Detalles Bibliográficos
Autores principales: Hou, Ying, Duan, Yin-Rong, Ding, Man-Hua, Tang, Lin-Li, Zeng, Fei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9362102/
https://www.ncbi.nlm.nih.gov/pubmed/36043113
http://dx.doi.org/10.1039/d2ra03773d
Descripción
Sumario:In this work, we developed a new method for the preparation of phenanthrene[2]arene on a large-scale. Meanwhile, the synthetic phenanthrene[2]arene has been successfully used as nonporous adaptive crystals for the separation of para-xylene (pX) from xylene isomers. The crystal structure revealed that one host molecule can adsorb one pX molecule to form the 1@pX complex, in which pX is located in the cavity of the host.

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