Integration of plasmonic AgPd alloy nanoparticles with single-layer graphitic carbon nitride as Mott-Schottky junction toward photo-promoted H(2) evolution

Plasmonic AgPd alloy nanoparticles (AgPd(NPs)) decorated on single-layer carbon nitride (AgPd(NPs)/SLCN) for the designing of the Mott-Schottky junction were constructed with the ultrasonically assisted hydrothermal method and used toward photo evolution H(2) from formic acid (FA) at near room tempe...

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Autores principales: Gholipour, Behnam, Zonouzi, Afsaneh, Shokouhimehr, Mohammadreza, Rostamnia, Sadegh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9363438/
https://www.ncbi.nlm.nih.gov/pubmed/35945424
http://dx.doi.org/10.1038/s41598-022-17238-4
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author Gholipour, Behnam
Zonouzi, Afsaneh
Shokouhimehr, Mohammadreza
Rostamnia, Sadegh
author_facet Gholipour, Behnam
Zonouzi, Afsaneh
Shokouhimehr, Mohammadreza
Rostamnia, Sadegh
author_sort Gholipour, Behnam
collection PubMed
description Plasmonic AgPd alloy nanoparticles (AgPd(NPs)) decorated on single-layer carbon nitride (AgPd(NPs)/SLCN) for the designing of the Mott-Schottky junction were constructed with the ultrasonically assisted hydrothermal method and used toward photo evolution H(2) from formic acid (FA) at near room temperature (30 °C). The Pd atom contains active sites that are synergistically boosted by the localized surface plasmon resonance (LSPR) effect of Ag atoms, leading to considerably enhanced photocatalytic properties. The photoactive AgPd(NPs)/SLCN obtained supreme catalytic activity to produce 50 mL of gas (H(2) + CO(2)) with the initial turnover frequency of 224 h(-1) under light irradiation. The catalyst showed stable catalytic performance during successive cycles.
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spelling pubmed-93634382022-08-11 Integration of plasmonic AgPd alloy nanoparticles with single-layer graphitic carbon nitride as Mott-Schottky junction toward photo-promoted H(2) evolution Gholipour, Behnam Zonouzi, Afsaneh Shokouhimehr, Mohammadreza Rostamnia, Sadegh Sci Rep Article Plasmonic AgPd alloy nanoparticles (AgPd(NPs)) decorated on single-layer carbon nitride (AgPd(NPs)/SLCN) for the designing of the Mott-Schottky junction were constructed with the ultrasonically assisted hydrothermal method and used toward photo evolution H(2) from formic acid (FA) at near room temperature (30 °C). The Pd atom contains active sites that are synergistically boosted by the localized surface plasmon resonance (LSPR) effect of Ag atoms, leading to considerably enhanced photocatalytic properties. The photoactive AgPd(NPs)/SLCN obtained supreme catalytic activity to produce 50 mL of gas (H(2) + CO(2)) with the initial turnover frequency of 224 h(-1) under light irradiation. The catalyst showed stable catalytic performance during successive cycles. Nature Publishing Group UK 2022-08-09 /pmc/articles/PMC9363438/ /pubmed/35945424 http://dx.doi.org/10.1038/s41598-022-17238-4 Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Gholipour, Behnam
Zonouzi, Afsaneh
Shokouhimehr, Mohammadreza
Rostamnia, Sadegh
Integration of plasmonic AgPd alloy nanoparticles with single-layer graphitic carbon nitride as Mott-Schottky junction toward photo-promoted H(2) evolution
title Integration of plasmonic AgPd alloy nanoparticles with single-layer graphitic carbon nitride as Mott-Schottky junction toward photo-promoted H(2) evolution
title_full Integration of plasmonic AgPd alloy nanoparticles with single-layer graphitic carbon nitride as Mott-Schottky junction toward photo-promoted H(2) evolution
title_fullStr Integration of plasmonic AgPd alloy nanoparticles with single-layer graphitic carbon nitride as Mott-Schottky junction toward photo-promoted H(2) evolution
title_full_unstemmed Integration of plasmonic AgPd alloy nanoparticles with single-layer graphitic carbon nitride as Mott-Schottky junction toward photo-promoted H(2) evolution
title_short Integration of plasmonic AgPd alloy nanoparticles with single-layer graphitic carbon nitride as Mott-Schottky junction toward photo-promoted H(2) evolution
title_sort integration of plasmonic agpd alloy nanoparticles with single-layer graphitic carbon nitride as mott-schottky junction toward photo-promoted h(2) evolution
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9363438/
https://www.ncbi.nlm.nih.gov/pubmed/35945424
http://dx.doi.org/10.1038/s41598-022-17238-4
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