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Photocatalytic activity of layered MoS(2) in the reductive degradation of bromophenol blue
Molybdenum disulphide (MoS(2)) is a layered material with interesting photocatalytic properties. In this study, a layered MoS(2) was produced using a hydrothermal method. The obtained material was characterised by XRD (X-ray diffraction), XPS (X-ray photoelectron spectroscopy), SEM (scanning electro...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9366594/ https://www.ncbi.nlm.nih.gov/pubmed/36105982 http://dx.doi.org/10.1039/d2ra03362c |
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author | Kisała, Joanna Ferraria, Ana M. Mitina, Nataliya Cieniek, Bogumił Krzemiński, Piotr Pogocki, Dariusz Nebesnyi, Roman Zaichenko, Oleksandr Bobitski, Yaroslav |
author_facet | Kisała, Joanna Ferraria, Ana M. Mitina, Nataliya Cieniek, Bogumił Krzemiński, Piotr Pogocki, Dariusz Nebesnyi, Roman Zaichenko, Oleksandr Bobitski, Yaroslav |
author_sort | Kisała, Joanna |
collection | PubMed |
description | Molybdenum disulphide (MoS(2)) is a layered material with interesting photocatalytic properties. In this study, a layered MoS(2) was produced using a hydrothermal method. The obtained material was characterised by XRD (X-ray diffraction), XPS (X-ray photoelectron spectroscopy), SEM (scanning electron microscopy), UV-Vis spectroscopy, DLS (dynamic light scattering), and zeta potential analysis. For the evaluation of the photocatalytic properties of layered MoS(2), a solution of bromophenol blue (BPB) and the catalyst was illuminated for 120 minutes. According to the experimental results, MoS(2) exhibited excellent catalytic activity in BPB degradation. The MoS(2) preparation method enabled improved light harvesting, avoided fast charge recombination (related to bulk MoS(2)), and created a large number of suitable electron transfer sites for photocatalytic reactions. Simulation of BPB decay and bromide production was carried out for a further understanding of MoS(2) photocatalytic action. The simulation results proved the reduction mechanism of BPB photodegradation. |
format | Online Article Text |
id | pubmed-9366594 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-93665942022-09-13 Photocatalytic activity of layered MoS(2) in the reductive degradation of bromophenol blue Kisała, Joanna Ferraria, Ana M. Mitina, Nataliya Cieniek, Bogumił Krzemiński, Piotr Pogocki, Dariusz Nebesnyi, Roman Zaichenko, Oleksandr Bobitski, Yaroslav RSC Adv Chemistry Molybdenum disulphide (MoS(2)) is a layered material with interesting photocatalytic properties. In this study, a layered MoS(2) was produced using a hydrothermal method. The obtained material was characterised by XRD (X-ray diffraction), XPS (X-ray photoelectron spectroscopy), SEM (scanning electron microscopy), UV-Vis spectroscopy, DLS (dynamic light scattering), and zeta potential analysis. For the evaluation of the photocatalytic properties of layered MoS(2), a solution of bromophenol blue (BPB) and the catalyst was illuminated for 120 minutes. According to the experimental results, MoS(2) exhibited excellent catalytic activity in BPB degradation. The MoS(2) preparation method enabled improved light harvesting, avoided fast charge recombination (related to bulk MoS(2)), and created a large number of suitable electron transfer sites for photocatalytic reactions. Simulation of BPB decay and bromide production was carried out for a further understanding of MoS(2) photocatalytic action. The simulation results proved the reduction mechanism of BPB photodegradation. The Royal Society of Chemistry 2022-08-11 /pmc/articles/PMC9366594/ /pubmed/36105982 http://dx.doi.org/10.1039/d2ra03362c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Kisała, Joanna Ferraria, Ana M. Mitina, Nataliya Cieniek, Bogumił Krzemiński, Piotr Pogocki, Dariusz Nebesnyi, Roman Zaichenko, Oleksandr Bobitski, Yaroslav Photocatalytic activity of layered MoS(2) in the reductive degradation of bromophenol blue |
title | Photocatalytic activity of layered MoS(2) in the reductive degradation of bromophenol blue |
title_full | Photocatalytic activity of layered MoS(2) in the reductive degradation of bromophenol blue |
title_fullStr | Photocatalytic activity of layered MoS(2) in the reductive degradation of bromophenol blue |
title_full_unstemmed | Photocatalytic activity of layered MoS(2) in the reductive degradation of bromophenol blue |
title_short | Photocatalytic activity of layered MoS(2) in the reductive degradation of bromophenol blue |
title_sort | photocatalytic activity of layered mos(2) in the reductive degradation of bromophenol blue |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9366594/ https://www.ncbi.nlm.nih.gov/pubmed/36105982 http://dx.doi.org/10.1039/d2ra03362c |
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