Replacement of Molybdenum by Tungsten in a Biomimetic Complex Leads to an Increase in Oxygen Atom Transfer Catalytic Activity

[Image: see text] Upon replacement of molybdenum by tungsten in DMSO reductase isolated from the Rhodobacteraceae family, the derived enzyme catalyzes DMSO reduction faster. To better understand this behavior, we synthesized two tungsten(VI) dioxido complexes [W(VI)O(2)L(2)] with pyridine- (PyS) and...

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Detalles Bibliográficos
Autores principales: Ćorović, Miljan Z., Wiedemaier, Fabian, Belaj, Ferdinand, Mösch-Zanetti, Nadia C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367641/
https://www.ncbi.nlm.nih.gov/pubmed/35894844
http://dx.doi.org/10.1021/acs.inorgchem.2c01868

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367641/
https://www.ncbi.nlm.nih.gov/pubmed/35894844
http://dx.doi.org/10.1021/acs.inorgchem.2c01868

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