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Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations

In situ mining is a practical and feasible technology for extracting oil shale. However, the extracted oil shale is subject to formation stress. This study systematically investigates the pyrolysis–mechanics–seepage problems of oil shale exploitation, which are subject to thermomechanical coupling u...

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Autores principales: Wang, Lei, Su, Jianzheng, Yang, Dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9369511/
https://www.ncbi.nlm.nih.gov/pubmed/35955300
http://dx.doi.org/10.3390/ma15155368
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author Wang, Lei
Su, Jianzheng
Yang, Dong
author_facet Wang, Lei
Su, Jianzheng
Yang, Dong
author_sort Wang, Lei
collection PubMed
description In situ mining is a practical and feasible technology for extracting oil shale. However, the extracted oil shale is subject to formation stress. This study systematically investigates the pyrolysis–mechanics–seepage problems of oil shale exploitation, which are subject to thermomechanical coupling using a thermal simulation experimental device representing a closed system, high-temperature rock mechanics testing system, and high-temperature triaxial permeability testing device. The results reveal the following. (i) The yield of gaseous hydrocarbon in the closed system increases throughout the pyrolysis reaction. Due to secondary cracking, the production of light and heavy hydrocarbon components first increases, and then decreases during the pyrolysis reaction. The parallel first-order reaction kinetic model shows a good fit with the pyrolysis and hydrocarbon generation processes of oil shale. With increasing temperature, the hydrocarbon generation conversion rate gradually increases, and the uniaxial compressive strength of oil shale was found to initially decrease and then increase. The compressive strength was the lowest at 400 °C, and the conversion rate of hydrocarbon formation gradually increased. The transformation of kaolinite into metakaolinite at high temperatures is the primary reason for the increase in compressive strength of oil shale at 400–600 °C. (ii) When the temperature is between 20 and 400 °C, the magnitude of oil shale permeability under stress is small (~10(−2) md). When the temperature exceeds 400 °C, the permeability of the oil shale is large, and it decreases approximately linearly with increasing pore pressure, which is attributed to the joint action of the gas slippage effect, adsorption effect, and effective stress. The results of this research provide a basis for high efficiency in situ exploitation of oil shale.
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spelling pubmed-93695112022-08-12 Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations Wang, Lei Su, Jianzheng Yang, Dong Materials (Basel) Article In situ mining is a practical and feasible technology for extracting oil shale. However, the extracted oil shale is subject to formation stress. This study systematically investigates the pyrolysis–mechanics–seepage problems of oil shale exploitation, which are subject to thermomechanical coupling using a thermal simulation experimental device representing a closed system, high-temperature rock mechanics testing system, and high-temperature triaxial permeability testing device. The results reveal the following. (i) The yield of gaseous hydrocarbon in the closed system increases throughout the pyrolysis reaction. Due to secondary cracking, the production of light and heavy hydrocarbon components first increases, and then decreases during the pyrolysis reaction. The parallel first-order reaction kinetic model shows a good fit with the pyrolysis and hydrocarbon generation processes of oil shale. With increasing temperature, the hydrocarbon generation conversion rate gradually increases, and the uniaxial compressive strength of oil shale was found to initially decrease and then increase. The compressive strength was the lowest at 400 °C, and the conversion rate of hydrocarbon formation gradually increased. The transformation of kaolinite into metakaolinite at high temperatures is the primary reason for the increase in compressive strength of oil shale at 400–600 °C. (ii) When the temperature is between 20 and 400 °C, the magnitude of oil shale permeability under stress is small (~10(−2) md). When the temperature exceeds 400 °C, the permeability of the oil shale is large, and it decreases approximately linearly with increasing pore pressure, which is attributed to the joint action of the gas slippage effect, adsorption effect, and effective stress. The results of this research provide a basis for high efficiency in situ exploitation of oil shale. MDPI 2022-08-04 /pmc/articles/PMC9369511/ /pubmed/35955300 http://dx.doi.org/10.3390/ma15155368 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wang, Lei
Su, Jianzheng
Yang, Dong
Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations
title Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations
title_full Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations
title_fullStr Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations
title_full_unstemmed Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations
title_short Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations
title_sort study on pyrolysis–mechanics–seepage behavior of oil shale in a closed system subject to real-time temperature variations
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9369511/
https://www.ncbi.nlm.nih.gov/pubmed/35955300
http://dx.doi.org/10.3390/ma15155368
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