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Impact of ZnO Modifier Concentration on TeO(2) Glass Matrix for Optical and Gamma-Ray Shielding Capabilities

This study carried out a comparison of the optical and gamma ray shielding features of TeO(2) with and without ZnO modifier concentration. Incorporating ZnO into the TeO(2) network reduces the indirect band gap from 3.515–3.481 eV. When ZnO is added, refractive indices, dielectric constants, and opt...

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Autores principales: Aloraini, Dalal A., Sayyed, M. I., Kumar, Ashok, Yasmin, Sabina, Almuqrin, Aljawhara H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9369588/
https://www.ncbi.nlm.nih.gov/pubmed/35955277
http://dx.doi.org/10.3390/ma15155342
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author Aloraini, Dalal A.
Sayyed, M. I.
Kumar, Ashok
Yasmin, Sabina
Almuqrin, Aljawhara H.
author_facet Aloraini, Dalal A.
Sayyed, M. I.
Kumar, Ashok
Yasmin, Sabina
Almuqrin, Aljawhara H.
author_sort Aloraini, Dalal A.
collection PubMed
description This study carried out a comparison of the optical and gamma ray shielding features of TeO(2) with and without ZnO modifier concentration. Incorporating ZnO into the TeO(2) network reduces the indirect band gap from 3.515–3.481 eV. When ZnO is added, refractive indices, dielectric constants, and optical dielectric constants rise from 2.271–2.278, 5.156–5.191, and 4.156–4.191 accordingly. The transmission coefficient and reflection loss are in direct opposition to each other. With increasing ZnO concentration in the selected glasses, the values of molar refractivity and molar polarizability decrease from 18.767–15.018 cm(3)/mol and from 7.444 × 10(−24)–5.957 × 10(−24) cm(3), respectively, while the electronic polarizability rises from 8.244 × 10(24)–8.273 × 10(24), correspondingly. As expected by the metallization values, the glass systems are non-metallic. The linear attenuation coefficients (LAC) of the studied glass samples ensue through enhancing the photon energy range 0.0395–0.3443 MeV. There is a very slow decrease in the LAC from an energy of 0.1218–0.3443 MeV, yet there is a sharp decrease from an energy of 0.0401–0.0459 MeV. According to the obtained values of numerous shielding parameters such as LAC, MAC, HVL, MFP, and Z(eff) sample, Zn30 has shown the best radiation shielding ability comprising other studied samples.
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spelling pubmed-93695882022-08-12 Impact of ZnO Modifier Concentration on TeO(2) Glass Matrix for Optical and Gamma-Ray Shielding Capabilities Aloraini, Dalal A. Sayyed, M. I. Kumar, Ashok Yasmin, Sabina Almuqrin, Aljawhara H. Materials (Basel) Article This study carried out a comparison of the optical and gamma ray shielding features of TeO(2) with and without ZnO modifier concentration. Incorporating ZnO into the TeO(2) network reduces the indirect band gap from 3.515–3.481 eV. When ZnO is added, refractive indices, dielectric constants, and optical dielectric constants rise from 2.271–2.278, 5.156–5.191, and 4.156–4.191 accordingly. The transmission coefficient and reflection loss are in direct opposition to each other. With increasing ZnO concentration in the selected glasses, the values of molar refractivity and molar polarizability decrease from 18.767–15.018 cm(3)/mol and from 7.444 × 10(−24)–5.957 × 10(−24) cm(3), respectively, while the electronic polarizability rises from 8.244 × 10(24)–8.273 × 10(24), correspondingly. As expected by the metallization values, the glass systems are non-metallic. The linear attenuation coefficients (LAC) of the studied glass samples ensue through enhancing the photon energy range 0.0395–0.3443 MeV. There is a very slow decrease in the LAC from an energy of 0.1218–0.3443 MeV, yet there is a sharp decrease from an energy of 0.0401–0.0459 MeV. According to the obtained values of numerous shielding parameters such as LAC, MAC, HVL, MFP, and Z(eff) sample, Zn30 has shown the best radiation shielding ability comprising other studied samples. MDPI 2022-08-03 /pmc/articles/PMC9369588/ /pubmed/35955277 http://dx.doi.org/10.3390/ma15155342 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Aloraini, Dalal A.
Sayyed, M. I.
Kumar, Ashok
Yasmin, Sabina
Almuqrin, Aljawhara H.
Impact of ZnO Modifier Concentration on TeO(2) Glass Matrix for Optical and Gamma-Ray Shielding Capabilities
title Impact of ZnO Modifier Concentration on TeO(2) Glass Matrix for Optical and Gamma-Ray Shielding Capabilities
title_full Impact of ZnO Modifier Concentration on TeO(2) Glass Matrix for Optical and Gamma-Ray Shielding Capabilities
title_fullStr Impact of ZnO Modifier Concentration on TeO(2) Glass Matrix for Optical and Gamma-Ray Shielding Capabilities
title_full_unstemmed Impact of ZnO Modifier Concentration on TeO(2) Glass Matrix for Optical and Gamma-Ray Shielding Capabilities
title_short Impact of ZnO Modifier Concentration on TeO(2) Glass Matrix for Optical and Gamma-Ray Shielding Capabilities
title_sort impact of zno modifier concentration on teo(2) glass matrix for optical and gamma-ray shielding capabilities
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9369588/
https://www.ncbi.nlm.nih.gov/pubmed/35955277
http://dx.doi.org/10.3390/ma15155342
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